Enhanced ORR Activity of A‑Site-Deficient SrCo0.8Nb0.1Ti0.1O3−δ as a Bifunctional Air Electrode for Low-Temperature Solid Oxide Fuel Cells

• Published in: Energy & fuels 2023-05, Vol.37 (9), p.6740-6748
• Main Authors: Zhang, Qi, Qiu, Hao, Jiang, Shanshan, Liu, Yang, Xu, Jiahuan, Wang, Wei, Chen, Daifen, Su, Chao
• Format: Article
• Language: English
• Subjects: Fuel Cells
• ISSN: 0887-0624; 1520-5029
• DOI: 10.1021/acs.energyfuels.3c00545

Solid oxide fuel cells (SOFCs) working at intermediate and low temperatures (≤650 °C) demonstrate tremendous potential benefits including their ease of manipulation, improvement in durability, and utilization of metallic interconnects. However, the sluggish oxygen reduction reaction (ORR) of air electrodes at lower temperatures is the main reason for constraining their supply of power. In this work, an A-site-deficient perovskite Sr0.95Co0.8Nb0.1Ti0.1O3−δ (S0.95CNT) has been developed as a bifunctional air electrode for both oxygen-ion-conducting SOFCs (O-SOFCs) and proton-conducting SOFCs (H-SOFCs). The generation of 5% A-site deficiency in SrCo0.8Nb0.1Ti0.1O3−δ (S1CNT) could increase the concentration of oxygen vacancies, thus facilitating the ORR kinetics for intermediate and low-temperature solid oxide fuel cells (ILT-SOFCs). The S0.95CNT air electrode delivers excellent area specific resistances (ASRs) at 500 °C, with values of only 0.13 and 1.08 Ω cm2 for S0.95CNT on the Sm0.2Ce0.8O1.9 (SDC) and BaZr0.1Ce0.7Y0.1Yb0.1O3−δ (BZCYYb) electrolytes, respectively, and remarkable peak power densities (PPDs) at 600 °C for O-SOFCs and H-SOFCs of 1369 and 569 mW cm–2, respectively, both about 18% higher than that of S1CNT with no deficiency. Overall, this work supplies a simple and effective way to improve the ORR kinetics of S1CNT as the bifunctional air electrode for ILT-SOFCs.