Phosphorus-Doped CuMn2O4 Nanoflakes: A Highly Performed Electrocatalyst for Oxygen Evolution Reaction and Hydrogen Evolution Reaction in an Alkaline Environment

• Published in: Energy & fuels 2024-08, Vol.38 (16), p.15533-15542
• Main Authors: Albaqami, Munirah D., Nisa, Mehar Un, Mohammad, Saikh, Hussain Shah, Jafar, Rehman Baloch, Ateeq Ur, Abid, Abdul Ghafoor, Saleem, Shahroz
• Format: Article
• Language: English
• Subjects: Efficiency and Sustainability
• ISSN: 0887-0624; 1520-5029
• DOI: 10.1021/acs.energyfuels.4c00878

For hydrogen production, the greatest emphasis is on the development of economical and efficient bifunctional electrocatalysts. In the present work, P-doped CuMn2O4 on nickel foam (NF) is prepared. For the physical and structural analysis, XRD, FTIR, SEM, and BET techniques are performed. The optimized P0.3-CuMn2O4/NF shows the best OER and HER activity compared to other concentrations and pristine CuMn2O4/NF. P0.3-CuMn2O4/NF exhibits reduced OER and HER onset potentials of 1.4 and 0.095 V vs RHE, and overpotentials of 208 and 103 mV at 10 mA cm–2, respectively. For P0.3-CuMn2O4/NF, the kinetic study utilizing Tafel slope 32 and 44 mV dec–1 suggests more rapid OER and HER processes, respectively. Furthermore, following phosphorus doping, the turnover frequency (TOF) study shows enhanced intrinsic OER (TOF = 2.3 s–1 at η = 260 mV) and HER activity (TOF = 1.3 s–1 at η = 260 mV). P0.3-CuMn2O4/NF excellent OER and HER activities are supported by the double layer capacitance (C dl = 92 mF cm–2). Hence, P0.3-CuMn2O4/NF is a potential electrocatalyst for both processes in an alkaline environment because of its improved OER and HER performance.