Simultaneous Removal of NO and SO2 from Exhaust Gas by Cyclic Scrubbing and Online Supplementing pH-Buffered NaClO2 Solution

• Published in: Energy & fuels 2019-07, Vol.33 (7), p.6591-6599
• Main Authors: Han, Zhitao, Lan, Tian, Han, Zhiwei, Yang, Shaolong, Dong, Jingming, Sun, Deping, Yan, Zhijun, Pan, Xinxiang, Song, Liguo
• Format: Article
• Language: English
• ISSN: 0887-0624; 1520-5029
• DOI: 10.1021/acs.energyfuels.9b01106

Experiments were conducted to simultaneously remove NO and SO2 from simulated exhaust gas by cyclic scrubbing and online supplementing pH-buffered NaClO2 solutions in a bench-scale reactor. The effects of key operating parameters on pollutant removal performance had been investigated. The results suggested that an extremely high oxidant utilization rate could be obtained when the oxidant supplementing molar rate approached the oxidant consumption molar rate. Though co-existing SO2 in flue gas would consume a certain amount of the oxidant during the absorption process, the intermediate products of SO3 2– ions generated from SO2 hydrolysis might be in favor of NO2 absorption to some extent. The introduction of ethanol in scrubbing solution could enhance NO x removal performance largely, which was possibly because of its inhibition effect on SO3 2– oxidation. The reaction mechanism and reaction products in scrubbing solutions were also discussed roughly through theoretical calculations and ion chromatography analysis.