Rhodium Nanoparticle Anchoring on AlPO4 for Efficient Catalyst Sintering Suppression

• Published in: Chemistry of materials 2014-10, Vol.26 (19), p.5799-5805
• Main Authors: Machida, Masato, Minami, Saki, Ikeue, Keita, Hinokuma, Satoshi, Nagao, Yuki, Sato, Takahiro, Nakahara, Yunosuke
• Format: Article
• Language: eng ; jpn
• ISSN: 0897-4756; 1520-5002
• DOI: 10.1021/cm503061g

Rhodium catalysts exhibited higher dispersion with tridymite-type AlPO4 supports than with Al2O3 during thermal aging at 900 °C under an oxidizing atmosphere. The local structural analysis via X-ray photoelectron spectroscopy, transmission electron microscopy, X-ray absorption fine structure, and infrared spectroscopy suggested that the sintering of AlPO4-supported Rh nanoparticles was significantly suppressed because of anchoring via a Rh–O–P linkage at the interface between the metal and support. Most of the AlPO4 surface was terminated by phosphate P–OH groups, which were converted into a Rh–O–P linkage when Rh oxide (RhO x ) was loaded. This interaction enables the thin planar RhO x nanoparticles to establish close and stable contact with the AlPO4 surface. It differs from Rh–O–Al bonding in the oxide-supported catalyst Rh/Al2O3, which causes undesired solid reactions that yield deactivated phases. The Rh–O–P interfacial linkage was preserved under oxidizing and reducing atmospheres, which contrasts with conventional metal oxide supports that only present the anchoring effect under an oxidizing atmosphere. These experimental results agree with a density functional theory optimized coherent interface RhO x /AlPO4 model.