A New Mixed-Valence Ferrite with a Cubic Structure, YBaFe4O7: Spin-Glass-Like Behavior

• Published in: Chemistry of materials 2009-03, Vol.21 (6), p.1116-1122
• Main Authors: Caignaert, V, Abakumov, A. M, Pelloquin, D, Pralong, V, Maignan, A, Tendeloo, G. Van, Raveau, B
• Format: Article
• Language: English
• Subjects: Characterization of Materials; Magnetic Materials; Structural Characterization (including AFM, NMR, X-ray Diffraction, etc.)
• ISSN: 0897-4756; 1520-5002
• DOI: 10.1021/cm803312f

A new mixed-valence ferrite, YBaFe4O7, has been synthesized. Its unique cubic structure, with a = 8.9595(2) Å, is closely related to that of the hexagonal “114” oxides YBaCo4O7 and CaBaFe4O7. It consists of corner-sharing FeO4 tetrahedra, forming triangular and kagome layers parallel to (111)C. In fact, the YBaFe4O7 and CaBaFe4O7 structures can be described as two different “ccc” and “chch” close packings of [BaO3]∞ and [O4]∞ layers, respectively, whose tetrahedral cavities are occupied by Fe2+/Fe3+ cations. The local structure of YBaFe4O7 is characterized by a large amount of stacking faults originating from the presence of “hexagonal” layers in the “ccc” cubic close-packed YBaFe4O7 structure. In this way, they belong to the large family of spinels and hexagonal ferrites studied for their magnetic properties. Differently from all the ferrites and especially from CaBaFe4O7, which are ferrimagnetic, YBaFe4O7 is an insulating spin glass with T g = 50 K.