Construction of a Ag12 High-Nuclearity Metallamacrocyclic 3D Framework

An unprecedented high-nuclearity metallamacrocycle-based 3D silver framework with formula {[Ag2(C25H27N6O)2](CH3OH)(H2O)0.17} n (1), built on the basis of dodecanuclear silver building blocks, has been synthesized and characterized, and it shows strong phosphorescence emission at 10 K, which is a co...

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Bibliographic Details
Published in:Inorganic chemistry 2010-04, Vol.49 (8), p.3679-3681
Main Authors: Hu, Jiyong, Zhao, Jin’an, Guo, Qianqian, Hou, Hongwei, Fan, Yaoting
Format: Article
Language:English
Online Access:Get full text
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Summary:An unprecedented high-nuclearity metallamacrocycle-based 3D silver framework with formula {[Ag2(C25H27N6O)2](CH3OH)(H2O)0.17} n (1), built on the basis of dodecanuclear silver building blocks, has been synthesized and characterized, and it shows strong phosphorescence emission at 10 K, which is a consequence of the presence of intersystem crossing from singlet to triplet caused by the heavy-atom effect of silver ions.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic902450c