Bimetallic Nickel Aluminun Mediated Para-Selective Alkenylation of Pyridine: Direct Observation of η2,η1-Pyridine Ni(0)−Al(III) Intermediates Prior to C−H Bond Activation

We have presented new amino-NHC Ni−Al complex mediated para C−H bond activation for pyridine and quinolin, and isolated for the first time the intermediate structure of a bimetallic η2,η1-pyridine nickel aluminum complex prior to its C−H activation, which serves as key evidence for bimetallic cataly...

Full description

Saved in:
Bibliographic Details
Published in:Journal of the American Chemical Society 2010-09, Vol.132 (34), p.11887-11889
Main Authors: Tsai, Chung-Chih, Shih, Wei-Chih, Fang, Cyong-Hui, Li, Chia-Yi, Ong, Tiow-Gan, Yap, Glenn P. A
Format: Article
Language:eng ; jpn
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page 11889
container_issue 34
container_start_page 11887
container_title Journal of the American Chemical Society
container_volume 132
creator Tsai, Chung-Chih
Shih, Wei-Chih
Fang, Cyong-Hui
Li, Chia-Yi
Ong, Tiow-Gan
Yap, Glenn P. A
description We have presented new amino-NHC Ni−Al complex mediated para C−H bond activation for pyridine and quinolin, and isolated for the first time the intermediate structure of a bimetallic η2,η1-pyridine nickel aluminum complex prior to its C−H activation, which serves as key evidence for bimetallic catalysis.
doi_str_mv 10.1021/ja1061246
format article
fullrecord <record><control><sourceid>acs</sourceid><recordid>TN_cdi_acs_journals_10_1021_ja1061246</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>a949833688</sourcerecordid><originalsourceid>FETCH-LOGICAL-a968-e6dccbe0c904e1d43ea6c85a35a19ca870bccb38ea08fc028e0ac6c204ea33283</originalsourceid><addsrcrecordid>eNo9kM1OAjEUhRujiYgufINuTCBxtD8zpbgb8IdJUEhkPymdS1IonaQzkPAGrn0Sd7wFD-GTWERZ3dycL-dLDkLXlNxRwuj9XFEiKIvFCWrQhJEooUycogYhhEUdKfg5uqiqeXhjJmkDffXMEmplrdH4zegFWJza1dK4lcOvUBhVQ4HHyqvoHSzo2qwhAAtwG6tqUzpczvB4401hHDzgR-MDg0fTCvz6mO-27Ha3pdE_F0Qt0v7--ExtK8uyNs5cDX55sFV47E3pcV3ifkAGuFe6Aqd782_hJTqbKVvB1d9tosnz06Q_iIajl6yfDiPVFTICUWg9BaK7JAZaxByU0DJRPFG0q5XskGnIuQRF5EwTJoEoLTQLtOKcSd5EN4dapat8Xq68C7Kckny_cn5cmf8AC7V0Qg</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Bimetallic Nickel Aluminun Mediated Para-Selective Alkenylation of Pyridine: Direct Observation of η2,η1-Pyridine Ni(0)−Al(III) Intermediates Prior to C−H Bond Activation</title><source>American Chemical Society:Jisc Collections:American Chemical Society Read &amp; Publish Agreement 2022-2024 (Reading list)</source><creator>Tsai, Chung-Chih ; Shih, Wei-Chih ; Fang, Cyong-Hui ; Li, Chia-Yi ; Ong, Tiow-Gan ; Yap, Glenn P. A</creator><creatorcontrib>Tsai, Chung-Chih ; Shih, Wei-Chih ; Fang, Cyong-Hui ; Li, Chia-Yi ; Ong, Tiow-Gan ; Yap, Glenn P. A</creatorcontrib><description>We have presented new amino-NHC Ni−Al complex mediated para C−H bond activation for pyridine and quinolin, and isolated for the first time the intermediate structure of a bimetallic η2,η1-pyridine nickel aluminum complex prior to its C−H activation, which serves as key evidence for bimetallic catalysis.</description><identifier>ISSN: 0002-7863</identifier><identifier>EISSN: 1520-5126</identifier><identifier>DOI: 10.1021/ja1061246</identifier><language>eng ; jpn</language><publisher>American Chemical Society</publisher><ispartof>Journal of the American Chemical Society, 2010-09, Vol.132 (34), p.11887-11889</ispartof><rights>Copyright © 2010 American Chemical Society</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,778,782,27907,27908</link.rule.ids></links><search><creatorcontrib>Tsai, Chung-Chih</creatorcontrib><creatorcontrib>Shih, Wei-Chih</creatorcontrib><creatorcontrib>Fang, Cyong-Hui</creatorcontrib><creatorcontrib>Li, Chia-Yi</creatorcontrib><creatorcontrib>Ong, Tiow-Gan</creatorcontrib><creatorcontrib>Yap, Glenn P. A</creatorcontrib><title>Bimetallic Nickel Aluminun Mediated Para-Selective Alkenylation of Pyridine: Direct Observation of η2,η1-Pyridine Ni(0)−Al(III) Intermediates Prior to C−H Bond Activation</title><title>Journal of the American Chemical Society</title><addtitle>J. Am. Chem. Soc</addtitle><description>We have presented new amino-NHC Ni−Al complex mediated para C−H bond activation for pyridine and quinolin, and isolated for the first time the intermediate structure of a bimetallic η2,η1-pyridine nickel aluminum complex prior to its C−H activation, which serves as key evidence for bimetallic catalysis.</description><issn>0002-7863</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNo9kM1OAjEUhRujiYgufINuTCBxtD8zpbgb8IdJUEhkPymdS1IonaQzkPAGrn0Sd7wFD-GTWERZ3dycL-dLDkLXlNxRwuj9XFEiKIvFCWrQhJEooUycogYhhEUdKfg5uqiqeXhjJmkDffXMEmplrdH4zegFWJza1dK4lcOvUBhVQ4HHyqvoHSzo2qwhAAtwG6tqUzpczvB4401hHDzgR-MDg0fTCvz6mO-27Ha3pdE_F0Qt0v7--ExtK8uyNs5cDX55sFV47E3pcV3ifkAGuFe6Aqd782_hJTqbKVvB1d9tosnz06Q_iIajl6yfDiPVFTICUWg9BaK7JAZaxByU0DJRPFG0q5XskGnIuQRF5EwTJoEoLTQLtOKcSd5EN4dapat8Xq68C7Kckny_cn5cmf8AC7V0Qg</recordid><startdate>20100901</startdate><enddate>20100901</enddate><creator>Tsai, Chung-Chih</creator><creator>Shih, Wei-Chih</creator><creator>Fang, Cyong-Hui</creator><creator>Li, Chia-Yi</creator><creator>Ong, Tiow-Gan</creator><creator>Yap, Glenn P. A</creator><general>American Chemical Society</general><scope/></search><sort><creationdate>20100901</creationdate><title>Bimetallic Nickel Aluminun Mediated Para-Selective Alkenylation of Pyridine: Direct Observation of η2,η1-Pyridine Ni(0)−Al(III) Intermediates Prior to C−H Bond Activation</title><author>Tsai, Chung-Chih ; Shih, Wei-Chih ; Fang, Cyong-Hui ; Li, Chia-Yi ; Ong, Tiow-Gan ; Yap, Glenn P. A</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a968-e6dccbe0c904e1d43ea6c85a35a19ca870bccb38ea08fc028e0ac6c204ea33283</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng ; jpn</language><creationdate>2010</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Tsai, Chung-Chih</creatorcontrib><creatorcontrib>Shih, Wei-Chih</creatorcontrib><creatorcontrib>Fang, Cyong-Hui</creatorcontrib><creatorcontrib>Li, Chia-Yi</creatorcontrib><creatorcontrib>Ong, Tiow-Gan</creatorcontrib><creatorcontrib>Yap, Glenn P. A</creatorcontrib><jtitle>Journal of the American Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tsai, Chung-Chih</au><au>Shih, Wei-Chih</au><au>Fang, Cyong-Hui</au><au>Li, Chia-Yi</au><au>Ong, Tiow-Gan</au><au>Yap, Glenn P. A</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Bimetallic Nickel Aluminun Mediated Para-Selective Alkenylation of Pyridine: Direct Observation of η2,η1-Pyridine Ni(0)−Al(III) Intermediates Prior to C−H Bond Activation</atitle><jtitle>Journal of the American Chemical Society</jtitle><addtitle>J. Am. Chem. Soc</addtitle><date>2010-09-01</date><risdate>2010</risdate><volume>132</volume><issue>34</issue><spage>11887</spage><epage>11889</epage><pages>11887-11889</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><abstract>We have presented new amino-NHC Ni−Al complex mediated para C−H bond activation for pyridine and quinolin, and isolated for the first time the intermediate structure of a bimetallic η2,η1-pyridine nickel aluminum complex prior to its C−H activation, which serves as key evidence for bimetallic catalysis.</abstract><pub>American Chemical Society</pub><doi>10.1021/ja1061246</doi><tpages>3</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0002-7863
ispartof Journal of the American Chemical Society, 2010-09, Vol.132 (34), p.11887-11889
issn 0002-7863
1520-5126
language eng ; jpn
recordid cdi_acs_journals_10_1021_ja1061246
source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
title Bimetallic Nickel Aluminun Mediated Para-Selective Alkenylation of Pyridine: Direct Observation of η2,η1-Pyridine Ni(0)−Al(III) Intermediates Prior to C−H Bond Activation
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-17T01%3A00%3A38IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Bimetallic%20Nickel%20Aluminun%20Mediated%20Para-Selective%20Alkenylation%20of%20Pyridine:%20Direct%20Observation%20of%20%CE%B72,%CE%B71-Pyridine%20Ni(0)%E2%88%92Al(III)%20Intermediates%20Prior%20to%20C%E2%88%92H%20Bond%20Activation&rft.jtitle=Journal%20of%20the%20American%20Chemical%20Society&rft.au=Tsai,%20Chung-Chih&rft.date=2010-09-01&rft.volume=132&rft.issue=34&rft.spage=11887&rft.epage=11889&rft.pages=11887-11889&rft.issn=0002-7863&rft.eissn=1520-5126&rft_id=info:doi/10.1021/ja1061246&rft_dat=%3Cacs%3Ea949833688%3C/acs%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-a968-e6dccbe0c904e1d43ea6c85a35a19ca870bccb38ea08fc028e0ac6c204ea33283%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true