Carbon Networks Based on Dehydrobenzoannulenes. 3. Synthesis of Graphyne Substructures1

This Letter describes the synthesis of the first macrobicyclic subunits of the hypothetical all-carbon network graphyne. Key to synthetic success is an intramolecular Sonogashira cross-coupling sequence.

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Bibliographic Details
Published in:Organic letters 2000-04, Vol.2 (7), p.969-972
Main Authors: Kehoe, Joshua M, Kiley, James H, English, Jamieson J, Johnson, Charles A, Petersen, Ryan C, Haley, Michael M
Format: Article
Language:eng ; jpn
Online Access:Get full text
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Summary:This Letter describes the synthesis of the first macrobicyclic subunits of the hypothetical all-carbon network graphyne. Key to synthetic success is an intramolecular Sonogashira cross-coupling sequence.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol005623w