C-H...Pd（Ⅱ） interaction-driven homochiral M helix formation of neutral （R,R）-bis（pyrrol-2-ylmethyleneamino） cyclohexane palladium（Ⅱ） complex

A chiral complex of （R,R）-Pd was prepared by reaction of optically pure （R,R）-bis（pyrrol-2-ylmethyleneamino） cyclohexane ligand with Pd（OAc）2.2H2O under the base condition at room temperature. The weak intermolecular C-H...Pd interaction was found to be responsible for the homochiral M helix formati...

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Bibliographic Details
Published in:Chinese science bulletin 2007, Vol.52 (11), p.1581-1584
Main Author: SHAN XuFeng WU LiZhu ZHANG LiPing TUNG ChenHo
Format: Article
Language:English
Subjects:
X射线
交互作用
晶状结构
螺旋状结构
Online Access:Get full text
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Summary:A chiral complex of （R,R）-Pd was prepared by reaction of optically pure （R,R）-bis（pyrrol-2-ylmethyleneamino） cyclohexane ligand with Pd（OAc）2.2H2O under the base condition at room temperature. The weak intermolecular C-H...Pd interaction was found to be responsible for the homochiral M helix formation of the neutral, chiral, mononuclear （R,R）-Pd in the crystal packing.
ISSN:1001-6538
1861-9541