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Wet etching and infrared absorption of AlN bulk single crystals

The defects and the lattice perfection of an AlN(0001) single crystal grown by the physical vapor trans-port(PVT) method were investigated by wet etching, X-ray diffraction(XRD), and infrared absorption, respectively.A regular hexagonal etch pit density(EPD) of about 4000 cm-2 is observed on the(000...

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Published in:Journal of semiconductors 2009-07, Vol.30 (7), p.29-32
Main Author: 李巍巍 赵有文 董志远 杨俊 胡炜杰 客建红
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description The defects and the lattice perfection of an AlN(0001) single crystal grown by the physical vapor trans-port(PVT) method were investigated by wet etching, X-ray diffraction(XRD), and infrared absorption, respectively.A regular hexagonal etch pit density(EPD) of about 4000 cm-2 is observed on the(0001) Al surface of an AlN single crystal.The EPD exhibits a line array along the slip direction of the wurtzite structure, indicating a quite large thermal stress born by the crystal in the growth process.The XRD full width at half maximum(FWHM) of the single crystal is 35 arcsec, suggesting a good lattice perfection.Pronounced infrared absorption peaks are observed at wave numbers of 1790, 1850, 2000, and 3000 cm-1, respectively.These absorptions might relate to impurities O, C, Si and their complexes in AlN single crystals.
doi_str_mv 10.1088/1674-4926/30/7/073002
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subjects X射线衍射
散装
晶体生长
氮化铝
红外吸收
纤锌矿结构
蚀刻
铝单晶
title Wet etching and infrared absorption of AlN bulk single crystals
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