Amination of electron deficient aryl chlorides promoted by nano sized Mg（OH）_2 under transition metals free condition

This paper presents the amination reactions of electron deficient aryl chlorides promoted by Mg（OH）_2 without transition metals. Only using stoichiometric amount of nano sized Mg（OH）_2,good to moderate isolated yields could be achieved in N-methylpyr-rolidone （NMP） after 24 h at 150℃.

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Bibliographic Details
Published in:中国化学快报：英文版 2012, Vol.23 (2), p.137-140
Main Author: Zhi Hao Cui Zi Hui Meng Yan Qing Mi Peng Wang Qi Wang Lin Man Zhao Ke Jian Cui Fang Yu Zhi Bin Xu
Format: Article
Language:English
Subjects:
MG（OH）2
氯代芳烃
电子
纳米
胺化反应
自由状态
过渡金属
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Summary:This paper presents the amination reactions of electron deficient aryl chlorides promoted by Mg（OH）_2 without transition metals. Only using stoichiometric amount of nano sized Mg（OH）_2,good to moderate isolated yields could be achieved in N-methylpyr-rolidone （NMP） after 24 h at 150℃.
ISSN:1001-8417
1878-5964