Composition optimization and electrochemical characteristics of Co-free Fe-containing ABs-type hydrogen storage alloys through uniform design

• Published in: 中国稀土学报：英文版 2012, Vol.30 (4), p.361-366
• Main Author: 晁栋梁 陈云贵 朱昌荣 吴朝玲 朱丁
• Format: Article
• Language: English
• Subjects: ABS型; 含铁; 均匀设计; 成分优化; 电化学特性; 电化学阻抗谱; 贮氢合金; 高倍率放电性能
• ISSN: 1002-0721; 2509-4963

In order to reduce the cost of ABs-type hydrogen storage alloys, effects of substitution of Ce for La （A side） and Fe, Mn, Al for Ni （B side） on structural and electrochemical properties of （LaCe）;（NiFeMnAl）s alloys were studied systematically. To make component uniform and operation easy, uniform design （UD） method was introduced into the study of composition optimization of Co-free Fe-containing ABs-type alloys for the first time. X-ray diffraction （XRD） results showed that the designed alloys were of single CaCus-type structure phase. The replacement of Fe had a severe effect on electrochemical capacity, and the substitution of Fe and A1 had a synergetic action among the unit cell volume, cycling stability and high rate discharge property. Interestingly, it was found that the hydrogen storage alloys with excessively high plateau pressure showed a tilted line in Nyquist plot instead of the semicircle, and the current decayed rapidly to near zero at the beginning of the step in constant potential step （CPS）, indicating that electrochemical impedance spectra （EIS） and CPS cannot accurately measure the electrochemical kinetics process of the hydrogen storage alloys with excessively high plateau pressure.