An Efficient Palladium and Bis（2-pyridylmethyl）amine-based System for Suzuki-Miyaura Cross-Coupling under Aqueous and Aerobic Condition

A novel PdC12/bis（2-pyridylmethyl）amine-based ligand （1） catalytic system, which is water-soluble and air-stable, has been successfully synthesized and applied for Suzuki-Miyaura cross-coupling reaction. In the presence of catalytic amount of PdCl2/1 system, arylboronic acids can couple with a wide...

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Published in:中国化学：英文版 2012, Vol.30 (5), p.1114-1118
Main Author: 余建军 王利民 刘明涛 裘鋆 沈强 方磊 唐俊
Format: Article
Language:English
Subjects:
交叉偶联反应
吡啶
基础
好氧条件
氯化钯
耦合系统
芳基卤化物
铃木
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creator 余建军 王利民 刘明涛 裘鋆 沈强 方磊 唐俊
description A novel PdC12/bis（2-pyridylmethyl）amine-based ligand （1） catalytic system, which is water-soluble and air-stable, has been successfully synthesized and applied for Suzuki-Miyaura cross-coupling reaction. In the presence of catalytic amount of PdCl2/1 system, arylboronic acids can couple with a wide range of aryl halides, including aryl bromides and aryl chlorides. The reactions proceed under mild conditions to give excellent yields, and a wide range of functionalities is tolerated.
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subjects 交叉偶联反应
吡啶
基础
好氧条件
氯化钯
耦合系统
芳基卤化物
铃木
title An Efficient Palladium and Bis（2-pyridylmethyl）amine-based System for Suzuki-Miyaura Cross-Coupling under Aqueous and Aerobic Condition
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