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2D Naphthalenedisulfonate-cadmiun coordination polymer with 2,4,5-tri(4-pyridyl)-imidazole as a co-ligand: Structure and catalytic property

A new 2D coordination polymer, [Cd(tpim)(1,5-nds)]n (1), was constructed from 1,5-naphthalenedi- sulfonate (1,5-nds). 2.4,5-tri(4-pyridyl)-imidazole (tpim) and Cd(CH3COO)2.2H2O, which can be subsequently used to promote the epoxide ring-opening reaction of epoxides and amines with remarkable catalyt...

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Bibliographic Details
Published in:中国化学快报:英文版 2014 (2), p.243-246
Main Author: Xing-Wei Wang Hui Guo Meng-Jie Liu Xin-Yi Wang Dong-Sheng Deng
Format: Article
Language:English
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Summary:A new 2D coordination polymer, [Cd(tpim)(1,5-nds)]n (1), was constructed from 1,5-naphthalenedi- sulfonate (1,5-nds). 2.4,5-tri(4-pyridyl)-imidazole (tpim) and Cd(CH3COO)2.2H2O, which can be subsequently used to promote the epoxide ring-opening reaction of epoxides and amines with remarkable catalytic activity. In addition, the thermal and luminescent properties of I in the solid state were also investigated.
ISSN:1001-8417
1878-5964