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Energy transfer relation of a novel Ce3+/Pr3+/Eu3+ co-doped Sr2.975-xLaxAIO4+xF1-x solid solution phosphor

The photoluminescence properties and energy transfer of a new Ce3+/pr3+/Eu3+ co-doped solid-solution composi- tion of Sr2.975-xLaxAlO4+xF1-x (LSAF) phosphor are investigated. Upon doping Pr3+ into lattices of LSAF:Ce host, a shoulder emission peak is observed at about 620 nm, owing to the transition...

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Bibliographic Details
Published in:中国物理B:英文版 2014 (10), p.546-550
Main Author: 王延泽 马健 孙亮 李蕊 王达健
Format: Article
Language:English
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Summary:The photoluminescence properties and energy transfer of a new Ce3+/pr3+/Eu3+ co-doped solid-solution composi- tion of Sr2.975-xLaxAlO4+xF1-x (LSAF) phosphor are investigated. Upon doping Pr3+ into lattices of LSAF:Ce host, a shoulder emission peak is observed at about 620 nm, owing to the transition of 1D2 →3H4. Addition of Eu3+ to LSAF:Ce3+, Pr3+ phosphor results in a sharp emission peaked at 675 nm for the 5D0 →TF3 transition and an increase of the intensity of red emission for Pr3+ with increasing Eu3+ concentration. The pathways of energy transfer among Ce3+, Pr3+, and Eu3+ are proposed to be responsible for color addition of a red component to the primary yellow emission, enabling a potential adjustable color for blue excitable warm white.
ISSN:1674-1056
2058-3834