Pd-Catalyzed Synthesis of a-Awl Vinylphosphonates via Suzuki Arylation of a-Phosphonovinyl Nonaflates

The first palladium-catalyzed method for the arylation of α-phosphonovinyl nonaflates is described. Using a catalyst comprised of Pd（OAc）2 and SPhos, terminal and internal α-aryl vinylphosphonates could be efficiently ac- cessed under mild conditions. The reaction features a broad coupling partner s...

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Bibliographic Details
Published in:中国化学：英文版 2015 (10), p.1119-1123
Main Author: Meijuan Yuan Yewen Fang Li Zhang Xiaoping Jin Minjia Tao Qilin Ye Ruifeng Li Jinjian Li Hui Zheng Juejun Gu
Format: Article
Language:English
Subjects:
OAc
催化合成
多官能团
有效交流
膦酸酯
芳基化
钯催化剂
铃木
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Summary:The first palladium-catalyzed method for the arylation of α-phosphonovinyl nonaflates is described. Using a catalyst comprised of Pd（OAc）2 and SPhos, terminal and internal α-aryl vinylphosphonates could be efficiently ac- cessed under mild conditions. The reaction features a broad coupling partner scope and tolerates many functional groups.
ISSN:1001-604X
1614-7065