A Cobalt Supramolecular Compound Constructed from 4,6-Di（1-imidazolyl）- 1,3,5-triazine-2-one： Synthesis, Characterization and Magnetic Property

A cobalt（II） coordination polymer, [Co（dimto）2（H2O）2]·4H2O[1, dimto=4,6-di（1-imidazolyl）-1,3,5- triazine-2-one], has been prepared under solvothermal condition. Single-crystal structural analysis reveals that compound 1 crystallizes in the orthorhombic space group Ibca（No.73） with a=1.80696（12） nm,...

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Bibliographic Details
Published in:高等学校化学研究：英文版 2016 (2), p.184-187
Main Author: ZHENG Tianxing HAN Yide LIU Ningning
Format: Article
Language:English
Subjects:
X-射线粉末衍射
合成
咪唑基
磁性
表征
超分子化合物
配位聚合物
钴
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Summary:A cobalt（II） coordination polymer, [Co（dimto）2（H2O）2]·4H2O[1, dimto=4,6-di（1-imidazolyl）-1,3,5- triazine-2-one], has been prepared under solvothermal condition. Single-crystal structural analysis reveals that compound 1 crystallizes in the orthorhombic space group Ibca（No.73） with a=1.80696（12） nm, b=1.93224（11） nm, c=1.36798（10） nm, V=4.7763（5） nm3 and R1=0.0438. Compound 1 is a 3D supramolecular architecture composed of 1D wave-like chains with hydrogen bonds and π-π interactions. Compound 1 was further characterized by powder X-ray diffraction（PXRD）, infrared（IR） spectroscopy, thermogravimertic analysis（TG） and elemental analysis. Additionally, the magnetic property of compound 1 was also investigated.
ISSN:1005-9040
2210-3171