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Segregation growth of epitaxial graphene overlayers on Ni(111)
The orientation control of graphene overlayers on metal surface is an important issue which remains as a challenge in graphene growth on Ni surface. Here we have demonstrated that epitaxial graphene overlayers can be obtained by annealing a nickel carbide covered Ni(111) surface using in situ surfac...
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Published in: | 科学通报:英文版 2016 (19), p.1536-1542 |
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creator | Yang Yang Qiang Fu Wei Wei Xinhe Bao |
description | The orientation control of graphene overlayers on metal surface is an important issue which remains as a challenge in graphene growth on Ni surface. Here we have demonstrated that epitaxial graphene overlayers can be obtained by annealing a nickel carbide covered Ni(111) surface using in situ surface imaging techniques. Epitaxial graphene islands nucleate and grow via segregation of dissolved carbon atoms to the top surface at about 400 ℃. This is in contrast to a mixture of epitaxial and non-epi- taxial graphene domains grown directly on Ni(111) at 540 ℃. The different growth behaviors are related to the nucleation dynamics which is controlled by local carbon densities in the near surface region. |
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Here we have demonstrated that epitaxial graphene overlayers can be obtained by annealing a nickel carbide covered Ni(111) surface using in situ surface imaging techniques. Epitaxial graphene islands nucleate and grow via segregation of dissolved carbon atoms to the top surface at about 400 ℃. This is in contrast to a mixture of epitaxial and non-epi- taxial graphene domains grown directly on Ni(111) at 540 ℃. 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Here we have demonstrated that epitaxial graphene overlayers can be obtained by annealing a nickel carbide covered Ni(111) surface using in situ surface imaging techniques. Epitaxial graphene islands nucleate and grow via segregation of dissolved carbon atoms to the top surface at about 400 ℃. This is in contrast to a mixture of epitaxial and non-epi- taxial graphene domains grown directly on Ni(111) at 540 ℃. 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language | eng |
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source | ScienceDirect Journals; Alma/SFX Local Collection |
subjects | 定向控制 成核动力学 直接生长 石墨 表面偏析 覆盖层 金属表面 |
title | Segregation growth of epitaxial graphene overlayers on Ni(111) |
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