Indirect mineral carbonation of blast furnace slag with（NH4）2SO4 as a recyclable extractant

• Published in: 能源化学：英文版 2017 (5), p.927-935
• Main Author: Jinpeng Hu Weizao Liu Lin Wang Qiang Liu Fang Chen Hairong Yue Bin Liang Li Lü Ye Wang Guoquan Zhang Chun Li
• Format: Article
• Language: English
• ISSN: 2095-4956

Large quantities of CO2 and blast furnace slag are discharged in the iron and steel industry. Mineral carbonation of blast furnace slag can offer substantial CO2 emission reduction and comprehensive utilisation of the solid waste. In this study, a recyclable extractant,（NH4）2SO4, was used to extract calcium and magnesium from blast furnace slag（main phases of gehlenite and akermanite） by using low-temperature roasting to fix CO2 through aqueous carbonation. The process parameters and efficiency of the roasting extraction, mineralisation, and Al recovery were investigated in detail. The results showed that the extractions of Ca, Mg, and Al can reach almost 100% at an（NH4）2SO4-to-slag mass ratio of 3:1 and at 370°C in 1 h. Adjusting the p H value of the leaching solution of the roasted slag to 5.5 with the NH3 released during the roasting resulted in 99% Al precipitation, while co-precipitation of Mg was lower than 2%. The Mg-rich leachate after the depletion of Al and the leaching residue（main phases of CaSO4 and SiO2） were carbonated using（NH4）2CO3 and NH4HCO3 solutions, respectively, under mild conditions. Approximately 99% of Ca and 89% of Mg in the blast furnace slag were converted into CaCO3 and（NH4）2 Mg（CO3）2·4 H2O,respectively. The latter can be selectively decomposed to magnesium carbonate at 100-200 °C to recover the NH3 for reuse. In the present route, the total CO2 sequestration capacity per tonne of blast furnace slag reached up to 316 kg, and 313 kg of Al-rich precipitate, 1000 kg of carbonated product containing CaCO3 and SiO2, and 304 kg of carbonated product containing calcium carbonate and magnesium carbonate were recovered simultaneously. These products can be used, respectively, as raw materials for the production of electrolytic aluminium, cement, and light magnesium carbonate to replace natural resources.