La1-xSrxMO3 (M = Co, Mn, Cr) interconnects in a 4-leg all-oxide thermoelectric generator at high temperatures

• Published in: The Journal of physics and chemistry of solids 2022-08, Vol.167, p.110739, Article 110739
• Main Authors: Madathil, Reshma K., Schuler, Raphael, Norby, Truls
• Format: Article
• Language: English
• Subjects: Interconnect; La0.6Sr0.4CoO3 (LSC); NiO; Oxide; Thermoelectric generator; ZnO
• ISSN: 0022-3697; 1879-2553
• DOI: 10.1016/j.jpcs.2022.110739

We herein report tests at high temperatures of a 4-leg oxide thermoelectric generator consisting of two pairs of p-type Ni0.98Li0.02O (Li–NiO) and n-type Zn0.98Al0.02O (Al–ZnO), assembled with various conducting perovskite oxides as interconnects. Using a custom-built testing system, we evaluated performance and stability at a hot side (furnace) temperature of up to 1000 °C under temperature differences up to ΔT = 600 °C in air. With a La0.6Sr0.4CoO3 (LSC) interconnect, a maximum power output of 18 mW was achieved with TH = 940 and TC = 340 °C (ΔT = 600 °C). Power maxima with La0.8Sr0.2MnO3 (LSM) and La0.8Sr0.2CrO3 (LSCr) as interconnects were lower, 6 mW and 2 mW, respectively, under similar conditions, attributed to their lower thermal and electrical conductivities. This demonstrates the requirements and potential of oxide interconnects for stable use of all-oxide thermoelectric generators at high temperatures in ambient air. •Conducting perovskite oxide interconnects between NiO and ZnO thermoelectric legs.•Stable operation to 1000 °C in air in 4-leg thermoelectric generator (TEG).•High temperature gradient of 600 °C generates outputs in the mW range.•Interconnect La0.6Sr0.4CoO3 superior to La0.6Sr0.4MnO3 and La0.6Sr0.4CrO3.•Interconnect performance correlates with high electronic and thermal conductivities.