Polydopamine Nanomembranes as Adhesion Layers for Improved Corrosion Resistance in Low Carbon Steel

• Published in: Advanced engineering materials 2018-11, Vol.20 (11), p.n/a
• Main Authors: Ding, Zihao, Fatollahi‐Fard, Farzin, Kwon, Ik Soo, Pistorius, Petrus Christiaan, Bettinger, Christopher J.
• Format: Article
• Language: English
• Subjects: adhesion; corrosion; interface; polydopamine; polymer
• ISSN: 1438-1656; 1527-2648
• DOI: 10.1002/adem.201800621

Low‐carbon steel is an important commodity material, but poor corrosion resistance has a strong impact on its service life, which leads to great loss in economic development. Polymer coatings serve as barrier layers that confer corrosion resistance. However, robust adhesion between steels and polymer films operating in complex fluids is challenging. This study evaluates the utility of adhesion layers composed of polydopamine, an organic film formed through simultaneous deposition, and polymerization in aqueous phases. Here, polydopamine serves as an intermediary adhesion layer between metallic substrates and polymer coatings. The composition, microstructure, and electrochemical properties of polydopamine nanomembranes are characterized. The impact of polydopamine nanomembranes on adhesion and supplementary corrosion resistance of polymer‐based barrier layers is assessed using a functional assay. These results suggest that polydopamine‐based nanomembranes can serve as effective adhesion‐promoting intermediary layers that retard corrosion and prolong the service life of low‐carbon steels in certain applications. Low‐carbon steel suffers from a short service life due to its poor corrosion resistance. Polymeric coatings such as polyurethane are used as a protective layer to prevent corrosion, but robust adhesion between protective coatings and steels are challenging. Use of polydopamine as an intermediary drastically enhances adhesion, in turn, the service life of low‐carbon steels.