Size‐Selective Capture of Fluorocarbon Gases and Storage of Volatile Halogenated Organic Vapors with Low Boiling Points by Molecular‐Scale Cavities of Crystalline Pillar[n]quinones

Fluorocarbon gases are regarded as one of the largest contributors to serious environmental problems such as ozone‐depletion and global warming, and thus, the development of reclamation technologies is in great demand for reducing emission of such harmful compounds. So far, porous materials such as...

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Published in:Advanced functional materials 2024-04, Vol.34 (14), p.n/a
Main Authors: Ohtani, Shunsuke, Onishi, Katsuto, Wada, Keisuke, Hirohata, Tomoki, Inagi, Shinsuke, Pirillo, Jenny, Hijikata, Yuh, Mizuno, Motohiro, Kato, Kenichi, Ogoshi, Tomoki
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host‐guest systems
macrocycles
supramolecular chemistry
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cited_by cdi_FETCH-LOGICAL-c2894-ef27af96745b477ef14ec5834509d12142546524630f407a3f1182e2194e77353
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container_issue 14
container_start_page
container_title Advanced functional materials
container_volume 34
creator Ohtani, Shunsuke
Onishi, Katsuto
Wada, Keisuke
Hirohata, Tomoki
Inagi, Shinsuke
Pirillo, Jenny
Hijikata, Yuh
Mizuno, Motohiro
Kato, Kenichi
Ogoshi, Tomoki
description Fluorocarbon gases are regarded as one of the largest contributors to serious environmental problems such as ozone‐depletion and global warming, and thus, the development of reclamation technologies is in great demand for reducing emission of such harmful compounds. So far, porous materials such as zeolites, activated carbons, and metal‐organic frameworks (MOFs) have been examined as solid‐state absorbents for fluorocarbon gases. However, such porous materials often suffer from a lack of size‐selectivity in fluorocarbon gas uptakes due to the large‐sized cavities (>1 nm). Herein, it is reported that macrocyclic pillar[n]quinones (P[n]Q, n = 5 or 6) in crystalline state show size‐selective uptake for fluorocarbon gases owing to their molecular‐scale cavities (
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subjects host‐guest systems
macrocycles
supramolecular chemistry
title Size‐Selective Capture of Fluorocarbon Gases and Storage of Volatile Halogenated Organic Vapors with Low Boiling Points by Molecular‐Scale Cavities of Crystalline Pillar[n]quinones
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