Structure matching mechanism of nRu / FeCo 2 O 4 for highly‐selective oxidation of HMF toward FDCA

The selective oxidation of 5‐hydroxymethylfurfural (HMF) toward 2,5‐furandicarboxylic acid (FDCA) offers a promising green pathway to obtain monomers for the synthesis of biodegradable plastics. However, developing a high‐selectivity catalyst and understanding the catalytic mechanism are still great...

Full description

Saved in:
Bibliographic Details
Published in:AIChE journal 2024-12
Main Authors: Wang, Qiong‐Yu, Zhu, Yucheng, Jiang, Run, He, Gan, Zhao, Jun, Hu, Jun, Liu, Tao, Liu, Honghai, Loo, Siew‐Leng, Chen, Zhong, Wang, Jie‐Xin, Pan, Zhiyan, Li, Xiaonian, Cao, Dapeng, Hu, Zhong‐Ting
Format: Article
Language:English
Citations: Items that this one cites
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The selective oxidation of 5‐hydroxymethylfurfural (HMF) toward 2,5‐furandicarboxylic acid (FDCA) offers a promising green pathway to obtain monomers for the synthesis of biodegradable plastics. However, developing a high‐selectivity catalyst and understanding the catalytic mechanism are still great challenge. Here, we synthesize a nRu/FeCo 2 O 4 catalyst with Ru nanoparticles loaded on FeCo 2 O 4 . The nRu/FeCo 2 O 4 presents excellent HMF oxidation activity with 100% HMF conversion efficiency and 99% FDCA yield under optimized conditions. Density‐functional theory calculations further reveal the structure matching mechanism of nRu/FeCo 2 O 4 for high‐selective oxidation of HMF toward FDCA, that is, Ru loading in FeCo 2 O 4 provides a more suitable structure matching configuration for adsorption of two‐side chains in HMF, which could optimize the adsorption energy and thus increase reactivity. In short, this work provides a promising structure matching strategy for designing dual‐active‐site relay catalyst to oxidize ‐CHO and C‐OH groups in HMF and thus achieve highly‐selective oxidation of HMF toward FDCA.
ISSN:0001-1541
1547-5905
DOI:10.1002/aic.18671