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Binding CO 2 by a Cr 8 Metallacrown
The {Cr 8 } metallacrown [CrF(O 2 C t Bu) 2 ] 8 , containing a F‐lined internal cavity, shows high selectivity for CO 2 over N 2 . DFT calculations and absorption studies support the multiple binding of F‐groups to the C‐center of CO 2 (C⋅⋅⋅F 3.190(9)–3.389(9) Å), as confirmed by single‐crystal X‐ra...
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| Published in: | Angewandte Chemie 2017-05, Vol.129 (20), p.5619-5622 |
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| Main Authors: | , , , , , , , , , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c846-e04fc88dc23a32473cbf19d9130a70414d396cd16c6090c58204548771afc27b3 |
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| cites | cdi_FETCH-LOGICAL-c846-e04fc88dc23a32473cbf19d9130a70414d396cd16c6090c58204548771afc27b3 |
| container_end_page | 5622 |
| container_issue | 20 |
| container_start_page | 5619 |
| container_title | Angewandte Chemie |
| container_volume | 129 |
| creator | Vitórica‐Yrezábal, Iñigo J. Sava, Daniel Florin Timco, Grigore A. Brown, Martyn S. Savage, Mathew Godfrey, Harry G. W. Moreau, Florian Schröder, Martin Siperstein, Flor Brammer, Lee Yang, Sihai Attfield, Martin P. McDouall, Joseph J. W. Winpenny, Richard E. P. |
| description | The {Cr
8
} metallacrown [CrF(O
2
C
t
Bu)
2
]
8
, containing a F‐lined internal cavity, shows high selectivity for CO
2
over N
2
. DFT calculations and absorption studies support the multiple binding of F‐groups to the C‐center of CO
2
(C⋅⋅⋅F 3.190(9)–3.389(9) Å), as confirmed by single‐crystal X‐ray diffraction. |
| doi_str_mv | 10.1002/ange.201701726 |
| format | article |
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} metallacrown [CrF(O
2
C
t
Bu)
2
]
8
, containing a F‐lined internal cavity, shows high selectivity for CO
2
over N
2
. DFT calculations and absorption studies support the multiple binding of F‐groups to the C‐center of CO
2
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8
} metallacrown [CrF(O
2
C
t
Bu)
2
]
8
, containing a F‐lined internal cavity, shows high selectivity for CO
2
over N
2
. DFT calculations and absorption studies support the multiple binding of F‐groups to the C‐center of CO
2
(C⋅⋅⋅F 3.190(9)–3.389(9) Å), as confirmed by single‐crystal X‐ray diffraction.</description><issn>0044-8249</issn><issn>1521-3757</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNo9z0tLxDAUBeAgCtbRreuA69R7b9I8llp8wchsZh_SJB0qtUoiyPx7Z1CEA2d3Dh9j1wgtAtBtWHa5JUBzCOkT1mBHKKTpzClrAJQSlpQ7Zxe1vgGAJuMadnM_LWladrzfcOLDngfeF275a_4K8xxi-fheLtnZGOaar_56xbaPD9v-Waw3Ty_93VpEq7TIoMZobYokgyRlZBxGdMmhhGBAoUrS6ZhQRw0OYmcJVKesMRjGSGaQK9b-zh5Oay159J9leg9l7xH8UeiPQv8vlD-njUCK</recordid><startdate>20170508</startdate><enddate>20170508</enddate><creator>Vitórica‐Yrezábal, Iñigo J.</creator><creator>Sava, Daniel Florin</creator><creator>Timco, Grigore A.</creator><creator>Brown, Martyn S.</creator><creator>Savage, Mathew</creator><creator>Godfrey, Harry G. W.</creator><creator>Moreau, Florian</creator><creator>Schröder, Martin</creator><creator>Siperstein, Flor</creator><creator>Brammer, Lee</creator><creator>Yang, Sihai</creator><creator>Attfield, Martin P.</creator><creator>McDouall, Joseph J. W.</creator><creator>Winpenny, Richard E. P.</creator><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-2097-186X</orcidid><orcidid>https://orcid.org/0000-0002-5501-3971</orcidid><orcidid>https://orcid.org/0000-0001-7730-6938</orcidid><orcidid>https://orcid.org/0000-0001-8806-150X</orcidid><orcidid>https://orcid.org/0000-0001-6508-1751</orcidid><orcidid>https://orcid.org/0000-0002-7101-3963</orcidid></search><sort><creationdate>20170508</creationdate><title>Binding CO 2 by a Cr 8 Metallacrown</title><author>Vitórica‐Yrezábal, Iñigo J. ; Sava, Daniel Florin ; Timco, Grigore A. ; Brown, Martyn S. ; Savage, Mathew ; Godfrey, Harry G. W. ; Moreau, Florian ; Schröder, Martin ; Siperstein, Flor ; Brammer, Lee ; Yang, Sihai ; Attfield, Martin P. ; McDouall, Joseph J. W. ; Winpenny, Richard E. P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c846-e04fc88dc23a32473cbf19d9130a70414d396cd16c6090c58204548771afc27b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Vitórica‐Yrezábal, Iñigo J.</creatorcontrib><creatorcontrib>Sava, Daniel Florin</creatorcontrib><creatorcontrib>Timco, Grigore A.</creatorcontrib><creatorcontrib>Brown, Martyn S.</creatorcontrib><creatorcontrib>Savage, Mathew</creatorcontrib><creatorcontrib>Godfrey, Harry G. W.</creatorcontrib><creatorcontrib>Moreau, Florian</creatorcontrib><creatorcontrib>Schröder, Martin</creatorcontrib><creatorcontrib>Siperstein, Flor</creatorcontrib><creatorcontrib>Brammer, Lee</creatorcontrib><creatorcontrib>Yang, Sihai</creatorcontrib><creatorcontrib>Attfield, Martin P.</creatorcontrib><creatorcontrib>McDouall, Joseph J. W.</creatorcontrib><creatorcontrib>Winpenny, Richard E. P.</creatorcontrib><collection>CrossRef</collection><jtitle>Angewandte Chemie</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Vitórica‐Yrezábal, Iñigo J.</au><au>Sava, Daniel Florin</au><au>Timco, Grigore A.</au><au>Brown, Martyn S.</au><au>Savage, Mathew</au><au>Godfrey, Harry G. W.</au><au>Moreau, Florian</au><au>Schröder, Martin</au><au>Siperstein, Flor</au><au>Brammer, Lee</au><au>Yang, Sihai</au><au>Attfield, Martin P.</au><au>McDouall, Joseph J. W.</au><au>Winpenny, Richard E. P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Binding CO 2 by a Cr 8 Metallacrown</atitle><jtitle>Angewandte Chemie</jtitle><date>2017-05-08</date><risdate>2017</risdate><volume>129</volume><issue>20</issue><spage>5619</spage><epage>5622</epage><pages>5619-5622</pages><issn>0044-8249</issn><eissn>1521-3757</eissn><abstract>The {Cr
8
} metallacrown [CrF(O
2
C
t
Bu)
2
]
8
, containing a F‐lined internal cavity, shows high selectivity for CO
2
over N
2
. DFT calculations and absorption studies support the multiple binding of F‐groups to the C‐center of CO
2
(C⋅⋅⋅F 3.190(9)–3.389(9) Å), as confirmed by single‐crystal X‐ray diffraction.</abstract><doi>10.1002/ange.201701726</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0003-2097-186X</orcidid><orcidid>https://orcid.org/0000-0002-5501-3971</orcidid><orcidid>https://orcid.org/0000-0001-7730-6938</orcidid><orcidid>https://orcid.org/0000-0001-8806-150X</orcidid><orcidid>https://orcid.org/0000-0001-6508-1751</orcidid><orcidid>https://orcid.org/0000-0002-7101-3963</orcidid></addata></record> |
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| ispartof | Angewandte Chemie, 2017-05, Vol.129 (20), p.5619-5622 |
| issn | 0044-8249 1521-3757 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_ange_201701726 |
| source | Wiley-Blackwell Read & Publish Collection |
| title | Binding CO 2 by a Cr 8 Metallacrown |
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