Innenrücktitelbild: Dynamic‐to‐Static Planar Chirality Conversion in Pillar[5]arenes Regulated by Guest Solvents or Amplified by Crystallization (Angew. Chem. 19/2023)

Regulation of dynamic chirality and conversion of the regulated dynamic chirality to static chirality is challenging and important for their applications. In their Research Article (e202217971), Tomoki Ogoshi and co‐workers report the control and amplification of dynamic planar chirality of pillar[5...

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Bibliographic Details
Published in:Angewandte Chemie 2023-05, Vol.135 (19), p.n/a
Main Authors: Wada, Keisuke, Suzuki, Misaki, Kakuta, Takahiro, Yamagishi, Tada‐aki, Ohtani, Shunsuke, Fa, Shixin, Kato, Kenichi, Akine, Shigehisa, Ogoshi, Tomoki
Format: Article
Language:English
Subjects:
Chirality
Crystallization
Host–Guest Systems
Macrocycles
Pillar[n]Arenes
Online Access:Get full text
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Summary:Regulation of dynamic chirality and conversion of the regulated dynamic chirality to static chirality is challenging and important for their applications. In their Research Article (e202217971), Tomoki Ogoshi and co‐workers report the control and amplification of dynamic planar chirality of pillar[5]arene by guest solvents and crystallization, respectively. The regulated dynamic chirality was changed to static chirality by introducing bulky stoppers. The image shows the conversion of the dynamic‐to‐static planar chirality in pillar[5]arenes (cars) by introducing bulky stoppers (pit stop).
ISSN:0044-8249
1521-3757
DOI:10.1002/ange.202304371