Loading…
Luminescence Modulation in Boron‐Cluster‐Based Luminogens via Boron Isotope Effects
Recent advances in luminescent materials highlight the significant impact of hydrogen isotope effects on improving optoelectronic properties. However, the research on the influence of the boron isotope effects on photophysical properties remains underdeveloped. This study focused on exploring the bo...
Saved in:
Published in: | Angewandte Chemie 2024-11 |
---|---|
Main Authors: | , , , , , , , |
Format: | Article |
Language: | English |
Citations: | Items that this one cites |
Online Access: | Get full text |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
cited_by | |
---|---|
cites | cdi_FETCH-crossref_primary_10_1002_ange_2024104303 |
container_end_page | |
container_issue | |
container_start_page | |
container_title | Angewandte Chemie |
container_volume | |
creator | Ma, Wenli Zhang, Jianyu Zong, Jibo Ren, Hongyuan Tu, Deshuang Xu, Qinfeng Zhong Tang, Ben Yan, Hong |
description | Recent advances in luminescent materials highlight the significant impact of hydrogen isotope effects on improving optoelectronic properties. However, the research on the influence of the boron isotope effects on photophysical properties remains underdeveloped. This study focused on exploring the boron isotope effects in boron‐cluster‐based luminogens. In doing so, we designed and synthesized carborane‐based luminogens containing 98 % 10 B and 95 % 11 B, respectively, and observed distinct photophysical behaviors. Compared to the 10 B‐enriched luminogens, the 11 B‐enriched counterparts can significantly enhance luminescence efficiency, prolong emission lifetime, and reduce full‐width at half‐maximum. Additionally, increased thermal stability, redshifted B−H vibrations, and a fourfold enhanced electrochemiluminescence intensity have also been observed. On the other hand, the biological assessments of a 10 B‐enriched luminogen reveals low cytotoxicity, high boron uptake, and excellent fluorescence imaging capability, indicating the potential application in boron neutron capture therapy (BNCT). This work presents the first comprehensive exploration on the boron isotope effects in boron clusters, and provides valuable insights into the rational design of organic luminogens for advanced optoelectronic and biomedical applications. |
doi_str_mv | 10.1002/ange.202410430 |
format | article |
fullrecord | <record><control><sourceid>crossref</sourceid><recordid>TN_cdi_crossref_primary_10_1002_ange_202410430</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1002_ange_202410430</sourcerecordid><originalsourceid>FETCH-crossref_primary_10_1002_ange_2024104303</originalsourceid><addsrcrecordid>eNqVjs2KwjAURsOgMPVnO-u8QOtNmk51qygKuhNchlBvJdImktsKs5tHmGecJ_EX966-s_gOHMa-BCQCQI6MO2AiQSoBKoUPFolMijjNs7zDIgCl4rFUk0_WIzoCwLfMJxHbrdvaOqQCXYF84_dtZRrrHbeOT33w7v_3b1a11GC40tQQ7vld8Qd0xM_WPG58Rb7xJ-TzssSioQHrlqYiHD63z5LFfDtbxkXwRAFLfQq2NuFHC9C3fH3L16_89G3hAtgFUDs</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Luminescence Modulation in Boron‐Cluster‐Based Luminogens via Boron Isotope Effects</title><source>Wiley</source><creator>Ma, Wenli ; Zhang, Jianyu ; Zong, Jibo ; Ren, Hongyuan ; Tu, Deshuang ; Xu, Qinfeng ; Zhong Tang, Ben ; Yan, Hong</creator><creatorcontrib>Ma, Wenli ; Zhang, Jianyu ; Zong, Jibo ; Ren, Hongyuan ; Tu, Deshuang ; Xu, Qinfeng ; Zhong Tang, Ben ; Yan, Hong</creatorcontrib><description>Recent advances in luminescent materials highlight the significant impact of hydrogen isotope effects on improving optoelectronic properties. However, the research on the influence of the boron isotope effects on photophysical properties remains underdeveloped. This study focused on exploring the boron isotope effects in boron‐cluster‐based luminogens. In doing so, we designed and synthesized carborane‐based luminogens containing 98 % 10 B and 95 % 11 B, respectively, and observed distinct photophysical behaviors. Compared to the 10 B‐enriched luminogens, the 11 B‐enriched counterparts can significantly enhance luminescence efficiency, prolong emission lifetime, and reduce full‐width at half‐maximum. Additionally, increased thermal stability, redshifted B−H vibrations, and a fourfold enhanced electrochemiluminescence intensity have also been observed. On the other hand, the biological assessments of a 10 B‐enriched luminogen reveals low cytotoxicity, high boron uptake, and excellent fluorescence imaging capability, indicating the potential application in boron neutron capture therapy (BNCT). This work presents the first comprehensive exploration on the boron isotope effects in boron clusters, and provides valuable insights into the rational design of organic luminogens for advanced optoelectronic and biomedical applications.</description><identifier>ISSN: 0044-8249</identifier><identifier>EISSN: 1521-3757</identifier><identifier>DOI: 10.1002/ange.202410430</identifier><language>eng</language><ispartof>Angewandte Chemie, 2024-11</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-crossref_primary_10_1002_ange_2024104303</cites><orcidid>0000-0003-3993-0013</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Ma, Wenli</creatorcontrib><creatorcontrib>Zhang, Jianyu</creatorcontrib><creatorcontrib>Zong, Jibo</creatorcontrib><creatorcontrib>Ren, Hongyuan</creatorcontrib><creatorcontrib>Tu, Deshuang</creatorcontrib><creatorcontrib>Xu, Qinfeng</creatorcontrib><creatorcontrib>Zhong Tang, Ben</creatorcontrib><creatorcontrib>Yan, Hong</creatorcontrib><title>Luminescence Modulation in Boron‐Cluster‐Based Luminogens via Boron Isotope Effects</title><title>Angewandte Chemie</title><description>Recent advances in luminescent materials highlight the significant impact of hydrogen isotope effects on improving optoelectronic properties. However, the research on the influence of the boron isotope effects on photophysical properties remains underdeveloped. This study focused on exploring the boron isotope effects in boron‐cluster‐based luminogens. In doing so, we designed and synthesized carborane‐based luminogens containing 98 % 10 B and 95 % 11 B, respectively, and observed distinct photophysical behaviors. Compared to the 10 B‐enriched luminogens, the 11 B‐enriched counterparts can significantly enhance luminescence efficiency, prolong emission lifetime, and reduce full‐width at half‐maximum. Additionally, increased thermal stability, redshifted B−H vibrations, and a fourfold enhanced electrochemiluminescence intensity have also been observed. On the other hand, the biological assessments of a 10 B‐enriched luminogen reveals low cytotoxicity, high boron uptake, and excellent fluorescence imaging capability, indicating the potential application in boron neutron capture therapy (BNCT). This work presents the first comprehensive exploration on the boron isotope effects in boron clusters, and provides valuable insights into the rational design of organic luminogens for advanced optoelectronic and biomedical applications.</description><issn>0044-8249</issn><issn>1521-3757</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNqVjs2KwjAURsOgMPVnO-u8QOtNmk51qygKuhNchlBvJdImktsKs5tHmGecJ_EX966-s_gOHMa-BCQCQI6MO2AiQSoBKoUPFolMijjNs7zDIgCl4rFUk0_WIzoCwLfMJxHbrdvaOqQCXYF84_dtZRrrHbeOT33w7v_3b1a11GC40tQQ7vld8Qd0xM_WPG58Rb7xJ-TzssSioQHrlqYiHD63z5LFfDtbxkXwRAFLfQq2NuFHC9C3fH3L16_89G3hAtgFUDs</recordid><startdate>20241106</startdate><enddate>20241106</enddate><creator>Ma, Wenli</creator><creator>Zhang, Jianyu</creator><creator>Zong, Jibo</creator><creator>Ren, Hongyuan</creator><creator>Tu, Deshuang</creator><creator>Xu, Qinfeng</creator><creator>Zhong Tang, Ben</creator><creator>Yan, Hong</creator><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-3993-0013</orcidid></search><sort><creationdate>20241106</creationdate><title>Luminescence Modulation in Boron‐Cluster‐Based Luminogens via Boron Isotope Effects</title><author>Ma, Wenli ; Zhang, Jianyu ; Zong, Jibo ; Ren, Hongyuan ; Tu, Deshuang ; Xu, Qinfeng ; Zhong Tang, Ben ; Yan, Hong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-crossref_primary_10_1002_ange_2024104303</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ma, Wenli</creatorcontrib><creatorcontrib>Zhang, Jianyu</creatorcontrib><creatorcontrib>Zong, Jibo</creatorcontrib><creatorcontrib>Ren, Hongyuan</creatorcontrib><creatorcontrib>Tu, Deshuang</creatorcontrib><creatorcontrib>Xu, Qinfeng</creatorcontrib><creatorcontrib>Zhong Tang, Ben</creatorcontrib><creatorcontrib>Yan, Hong</creatorcontrib><collection>CrossRef</collection><jtitle>Angewandte Chemie</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ma, Wenli</au><au>Zhang, Jianyu</au><au>Zong, Jibo</au><au>Ren, Hongyuan</au><au>Tu, Deshuang</au><au>Xu, Qinfeng</au><au>Zhong Tang, Ben</au><au>Yan, Hong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Luminescence Modulation in Boron‐Cluster‐Based Luminogens via Boron Isotope Effects</atitle><jtitle>Angewandte Chemie</jtitle><date>2024-11-06</date><risdate>2024</risdate><issn>0044-8249</issn><eissn>1521-3757</eissn><abstract>Recent advances in luminescent materials highlight the significant impact of hydrogen isotope effects on improving optoelectronic properties. However, the research on the influence of the boron isotope effects on photophysical properties remains underdeveloped. This study focused on exploring the boron isotope effects in boron‐cluster‐based luminogens. In doing so, we designed and synthesized carborane‐based luminogens containing 98 % 10 B and 95 % 11 B, respectively, and observed distinct photophysical behaviors. Compared to the 10 B‐enriched luminogens, the 11 B‐enriched counterparts can significantly enhance luminescence efficiency, prolong emission lifetime, and reduce full‐width at half‐maximum. Additionally, increased thermal stability, redshifted B−H vibrations, and a fourfold enhanced electrochemiluminescence intensity have also been observed. On the other hand, the biological assessments of a 10 B‐enriched luminogen reveals low cytotoxicity, high boron uptake, and excellent fluorescence imaging capability, indicating the potential application in boron neutron capture therapy (BNCT). This work presents the first comprehensive exploration on the boron isotope effects in boron clusters, and provides valuable insights into the rational design of organic luminogens for advanced optoelectronic and biomedical applications.</abstract><doi>10.1002/ange.202410430</doi><orcidid>https://orcid.org/0000-0003-3993-0013</orcidid></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0044-8249 |
ispartof | Angewandte Chemie, 2024-11 |
issn | 0044-8249 1521-3757 |
language | eng |
recordid | cdi_crossref_primary_10_1002_ange_202410430 |
source | Wiley |
title | Luminescence Modulation in Boron‐Cluster‐Based Luminogens via Boron Isotope Effects |
url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-23T04%3A01%3A23IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Luminescence%20Modulation%20in%20Boron%E2%80%90Cluster%E2%80%90Based%20Luminogens%20via%20Boron%20Isotope%20Effects&rft.jtitle=Angewandte%20Chemie&rft.au=Ma,%20Wenli&rft.date=2024-11-06&rft.issn=0044-8249&rft.eissn=1521-3757&rft_id=info:doi/10.1002/ange.202410430&rft_dat=%3Ccrossref%3E10_1002_ange_202410430%3C/crossref%3E%3Cgrp_id%3Ecdi_FETCH-crossref_primary_10_1002_ange_2024104303%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |