Inside Cover: Highly Selective Synthesis of Iridium(III) Metalla[2]catenanes through Component Pre‐Orientation by π⋅⋅⋅π Stacking (Angew. Chem. Int. Ed. 18/2019)

The topology of interlinked metallacycles can be controlled through their substitution pattern. In their Communication on page 5882 ff., F. E. Hahn, G.‐X. Lin, and co‐workers describe the synthesis of metalla[2]catenanes from dinuclear iridium complexes and anthracene‐bridged dipyridyl ligands. Nonc...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2019-04, Vol.58 (18), p.5774-5774
Main Authors: Shan, Wei‐Long, Lin, Yue‐Jian, Hahn, F. Ekkehardt, Jin, Guo‐Xin
Format: Article
Language:English
Subjects:
half-sandwich iridium complexes
metallacatenanes
self-assembly
supramolecular chemistry
topology control
Online Access:Get full text
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Summary:The topology of interlinked metallacycles can be controlled through their substitution pattern. In their Communication on page 5882 ff., F. E. Hahn, G.‐X. Lin, and co‐workers describe the synthesis of metalla[2]catenanes from dinuclear iridium complexes and anthracene‐bridged dipyridyl ligands. Noncovalent π–π‐stacking interactions play a crucial role in the formation of these catenanes.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201903368