Reversible Encapsulation of Xenon and CH 2 Cl 2 in a Solid-State Molecular Organometallic Framework (Guest@SMOM)

Reversible encapsulation of CH Cl or Xe in a non-porous solid-state molecular organometallic framework of [Rh(Cy PCH PCy )(NBD)][BAr ] occurs in single-crystal to single-crystal transformations. These processes are probed by solid-state NMR spectroscopy, including Xe SSNMR. Non-covalent interactions...

Full description

Saved in:
Bibliographic Details
Published in:Angewandte Chemie International Edition 2019-11, Vol.58 (47), p.16873-16877
Main Authors: Martínez-Martínez, Antonio J, Rees, Nicholas H, Weller, Andrew S
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c1074-6129e278951a0336ce781a460b43da0e89cc3f7d554191be57059716c7f0d6e93
cites cdi_FETCH-LOGICAL-c1074-6129e278951a0336ce781a460b43da0e89cc3f7d554191be57059716c7f0d6e93
container_end_page 16877
container_issue 47
container_start_page 16873
container_title Angewandte Chemie International Edition
container_volume 58
creator Martínez-Martínez, Antonio J
Rees, Nicholas H
Weller, Andrew S
description Reversible encapsulation of CH Cl or Xe in a non-porous solid-state molecular organometallic framework of [Rh(Cy PCH PCy )(NBD)][BAr ] occurs in single-crystal to single-crystal transformations. These processes are probed by solid-state NMR spectroscopy, including Xe SSNMR. Non-covalent interactions with the -CF groups, and hydrophobic channels formed, of [BAr ] anions are shown to be important, and thus have similarity to the transport of substrates and products to and from the active site in metalloenzymes.
doi_str_mv 10.1002/anie.201910539
format article
fullrecord <record><control><sourceid>pubmed_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1002_anie_201910539</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>31539184</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1074-6129e278951a0336ce781a460b43da0e89cc3f7d554191be57059716c7f0d6e93</originalsourceid><addsrcrecordid>eNo9kM1Lw0AQxRdRbK1ePcoe9ZC6k81mk5sS-iG0FKyCt7DZTCS6-WA3Vfzv3VLtZeYxvDfwfoRcA5sCY-G9amuchgxSYIKnJ2QMIoSAS8lPvY44D2QiYEQunPvw_iRh8TkZcfBmSKIx6Z_xC62rC4N01mrVu51RQ921tKvoG7ZeqLak2ZKGNDN-1P5At52py2A7qAHpujOofcjSjX1XbdfgoIypNZ1b1eB3Zz_p7WKHbnjYrjfru0tyVinj8OpvT8jrfPaSLYPVZvGUPa4CDUxGQQxhiqFMUgGKcR5rlAmoKGZFxEvFMEm15pUshYh89wKFZCKVEGtZsTLGlE_I9PBX2845i1Xe27pR9icHlu_R5Xt0-RGdD9wcAv2uaLA82v9Z8V9HMmg8</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Reversible Encapsulation of Xenon and CH 2 Cl 2 in a Solid-State Molecular Organometallic Framework (Guest@SMOM)</title><source>Wiley</source><creator>Martínez-Martínez, Antonio J ; Rees, Nicholas H ; Weller, Andrew S</creator><creatorcontrib>Martínez-Martínez, Antonio J ; Rees, Nicholas H ; Weller, Andrew S</creatorcontrib><description>Reversible encapsulation of CH Cl or Xe in a non-porous solid-state molecular organometallic framework of [Rh(Cy PCH PCy )(NBD)][BAr ] occurs in single-crystal to single-crystal transformations. These processes are probed by solid-state NMR spectroscopy, including Xe SSNMR. Non-covalent interactions with the -CF groups, and hydrophobic channels formed, of [BAr ] anions are shown to be important, and thus have similarity to the transport of substrates and products to and from the active site in metalloenzymes.</description><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201910539</identifier><identifier>PMID: 31539184</identifier><language>eng</language><publisher>Germany</publisher><ispartof>Angewandte Chemie International Edition, 2019-11, Vol.58 (47), p.16873-16877</ispartof><rights>2019 The Authors. Published by Wiley-VCH Verlag GmbH &amp; Co. KGaA.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1074-6129e278951a0336ce781a460b43da0e89cc3f7d554191be57059716c7f0d6e93</citedby><cites>FETCH-LOGICAL-c1074-6129e278951a0336ce781a460b43da0e89cc3f7d554191be57059716c7f0d6e93</cites><orcidid>0000-0002-0684-1244 ; 0000-0003-1646-8081</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31539184$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Martínez-Martínez, Antonio J</creatorcontrib><creatorcontrib>Rees, Nicholas H</creatorcontrib><creatorcontrib>Weller, Andrew S</creatorcontrib><title>Reversible Encapsulation of Xenon and CH 2 Cl 2 in a Solid-State Molecular Organometallic Framework (Guest@SMOM)</title><title>Angewandte Chemie International Edition</title><addtitle>Angew Chem Int Ed Engl</addtitle><description>Reversible encapsulation of CH Cl or Xe in a non-porous solid-state molecular organometallic framework of [Rh(Cy PCH PCy )(NBD)][BAr ] occurs in single-crystal to single-crystal transformations. These processes are probed by solid-state NMR spectroscopy, including Xe SSNMR. Non-covalent interactions with the -CF groups, and hydrophobic channels formed, of [BAr ] anions are shown to be important, and thus have similarity to the transport of substrates and products to and from the active site in metalloenzymes.</description><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNo9kM1Lw0AQxRdRbK1ePcoe9ZC6k81mk5sS-iG0FKyCt7DZTCS6-WA3Vfzv3VLtZeYxvDfwfoRcA5sCY-G9amuchgxSYIKnJ2QMIoSAS8lPvY44D2QiYEQunPvw_iRh8TkZcfBmSKIx6Z_xC62rC4N01mrVu51RQ921tKvoG7ZeqLak2ZKGNDN-1P5At52py2A7qAHpujOofcjSjX1XbdfgoIypNZ1b1eB3Zz_p7WKHbnjYrjfru0tyVinj8OpvT8jrfPaSLYPVZvGUPa4CDUxGQQxhiqFMUgGKcR5rlAmoKGZFxEvFMEm15pUshYh89wKFZCKVEGtZsTLGlE_I9PBX2845i1Xe27pR9icHlu_R5Xt0-RGdD9wcAv2uaLA82v9Z8V9HMmg8</recordid><startdate>20191118</startdate><enddate>20191118</enddate><creator>Martínez-Martínez, Antonio J</creator><creator>Rees, Nicholas H</creator><creator>Weller, Andrew S</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-0684-1244</orcidid><orcidid>https://orcid.org/0000-0003-1646-8081</orcidid></search><sort><creationdate>20191118</creationdate><title>Reversible Encapsulation of Xenon and CH 2 Cl 2 in a Solid-State Molecular Organometallic Framework (Guest@SMOM)</title><author>Martínez-Martínez, Antonio J ; Rees, Nicholas H ; Weller, Andrew S</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1074-6129e278951a0336ce781a460b43da0e89cc3f7d554191be57059716c7f0d6e93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Martínez-Martínez, Antonio J</creatorcontrib><creatorcontrib>Rees, Nicholas H</creatorcontrib><creatorcontrib>Weller, Andrew S</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Martínez-Martínez, Antonio J</au><au>Rees, Nicholas H</au><au>Weller, Andrew S</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Reversible Encapsulation of Xenon and CH 2 Cl 2 in a Solid-State Molecular Organometallic Framework (Guest@SMOM)</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew Chem Int Ed Engl</addtitle><date>2019-11-18</date><risdate>2019</risdate><volume>58</volume><issue>47</issue><spage>16873</spage><epage>16877</epage><pages>16873-16877</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>Reversible encapsulation of CH Cl or Xe in a non-porous solid-state molecular organometallic framework of [Rh(Cy PCH PCy )(NBD)][BAr ] occurs in single-crystal to single-crystal transformations. These processes are probed by solid-state NMR spectroscopy, including Xe SSNMR. Non-covalent interactions with the -CF groups, and hydrophobic channels formed, of [BAr ] anions are shown to be important, and thus have similarity to the transport of substrates and products to and from the active site in metalloenzymes.</abstract><cop>Germany</cop><pmid>31539184</pmid><doi>10.1002/anie.201910539</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-0684-1244</orcidid><orcidid>https://orcid.org/0000-0003-1646-8081</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 1433-7851
ispartof Angewandte Chemie International Edition, 2019-11, Vol.58 (47), p.16873-16877
issn 1433-7851
1521-3773
language eng
recordid cdi_crossref_primary_10_1002_anie_201910539
source Wiley
title Reversible Encapsulation of Xenon and CH 2 Cl 2 in a Solid-State Molecular Organometallic Framework (Guest@SMOM)
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-26T08%3A44%3A51IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-pubmed_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Reversible%20Encapsulation%20of%20Xenon%20and%20CH%202%20Cl%202%20in%20a%20Solid-State%20Molecular%20Organometallic%20Framework%20(Guest@SMOM)&rft.jtitle=Angewandte%20Chemie%20International%20Edition&rft.au=Mart%C3%ADnez-Mart%C3%ADnez,%20Antonio%20J&rft.date=2019-11-18&rft.volume=58&rft.issue=47&rft.spage=16873&rft.epage=16877&rft.pages=16873-16877&rft.issn=1433-7851&rft.eissn=1521-3773&rft_id=info:doi/10.1002/anie.201910539&rft_dat=%3Cpubmed_cross%3E31539184%3C/pubmed_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c1074-6129e278951a0336ce781a460b43da0e89cc3f7d554191be57059716c7f0d6e93%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/31539184&rfr_iscdi=true