Some ferrocenyl Schiff bases with nonlinear optical properties

Eleven new ferrocenyl Schiff bases containing a benzene ring and CN in a conjugating chain have been synthesized by facile methods and characterized by 1H NMR, elemental analysis and fast atom bombardment mass spectrometry. Cyclic voltammetry was used to determine their electrochemical properties a...

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Bibliographic Details
Published in:Applied organometallic chemistry 2003-09, Vol.17 (9), p.706-710
Main Authors: Huang, Guo-Sheng, Liang, Yong-Min, Wu, Xiao-Li, Liu, Wei-Min, Ma, Yong-Xiang
Format: Article
Language:English
Subjects:
Chemistry
cyclic voltammetry
electronic absorption spectra
Exact sciences and technology
ferrocenyl Schiff base
NLO
Organic chemistry
Organometalloidal and organometallic compounds
powder SHG
Preparations and properties
Transition metals derivatives
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Summary:Eleven new ferrocenyl Schiff bases containing a benzene ring and CN in a conjugating chain have been synthesized by facile methods and characterized by 1H NMR, elemental analysis and fast atom bombardment mass spectrometry. Cyclic voltammetry was used to determine their electrochemical properties and electron‐withdrawing effects. It is shown that these pull–push ferrocenyl compounds have nonlinear optical responses according to their electronic absorption spectra and powder second harmonic generation measurements. Copyright © 2003 John Wiley & Sons, Ltd.
ISSN:0268-2605
1099-0739
DOI:10.1002/aoc.503