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Some ferrocenyl Schiff bases with nonlinear optical properties

Eleven new ferrocenyl Schiff bases containing a benzene ring and CN in a conjugating chain have been synthesized by facile methods and characterized by 1H NMR, elemental analysis and fast atom bombardment mass spectrometry. Cyclic voltammetry was used to determine their electrochemical properties a...

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Published in:	Applied organometallic chemistry 2003-09, Vol.17 (9), p.706-710
Main Authors:	Huang, Guo-Sheng, Liang, Yong-Min, Wu, Xiao-Li, Liu, Wei-Min, Ma, Yong-Xiang
Format:	Article
Language:	English
Subjects:	Chemistry cyclic voltammetry electronic absorption spectra Exact sciences and technology ferrocenyl Schiff base NLO Organic chemistry Organometalloidal and organometallic compounds powder SHG Preparations and properties Transition metals derivatives
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description	Eleven new ferrocenyl Schiff bases containing a benzene ring and CN in a conjugating chain have been synthesized by facile methods and characterized by 1H NMR, elemental analysis and fast atom bombardment mass spectrometry. Cyclic voltammetry was used to determine their electrochemical properties and electron‐withdrawing effects. It is shown that these pull–push ferrocenyl compounds have nonlinear optical responses according to their electronic absorption spectra and powder second harmonic generation measurements. Copyright © 2003 John Wiley & Sons, Ltd.
doi_str_mv	10.1002/aoc.503
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subjects	Chemistry cyclic voltammetry electronic absorption spectra Exact sciences and technology ferrocenyl Schiff base NLO Organic chemistry Organometalloidal and organometallic compounds powder SHG Preparations and properties Transition metals derivatives
title	Some ferrocenyl Schiff bases with nonlinear optical properties
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