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Ring-opening metathesis polymerization of cyclododecene using an electrochemically reduced tungsten-based catalyst
The ring‐opening metathesis polymerization of cyclododecene using an electrochemically reduced tungsten‐based catalyst (WCl6e−AlCH2Cl2) is described. In addition, the influence of reaction conditions on the polymerization yield was determined. The resulting polymer has been characterized by NMR,...
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| Published in: | Applied organometallic chemistry 2004-08, Vol.18 (8), p.375-379 |
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| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c3272-a2a0a821ca035243515faa17666fb09c11ef5702607c62468dd00d9ff5a469ac3 |
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| cites | cdi_FETCH-LOGICAL-c3272-a2a0a821ca035243515faa17666fb09c11ef5702607c62468dd00d9ff5a469ac3 |
| container_end_page | 379 |
| container_issue | 8 |
| container_start_page | 375 |
| container_title | Applied organometallic chemistry |
| container_volume | 18 |
| creator | Karabulut, Solmaz Çetinkaya, Sevil Düz, Bülent İmamoǧlu, Yavuz |
| description | The ring‐opening metathesis polymerization of cyclododecene using an electrochemically reduced tungsten‐based catalyst (WCl6e−AlCH2Cl2) is described. In addition, the influence of reaction conditions on the polymerization yield was determined. The resulting polymer has been characterized by NMR, IR, gel permeation chromatography and differential scanning calorimetry. The glass transition temperature and melting point of the polydodecenamer are 19.6°C and 70.0°C respectively. Furthermore, cyclododecene has been polymerized into a low‐molecular‐weight polymer (12.0 × 103) with a polydispersity of 2.06 in high yields (94%). IR and NMR analysis indicate that the polydodecenamer has a high trans content (60%). Copyright © 2004 John Wiley & Sons, Ltd. |
| doi_str_mv | 10.1002/aoc.662 |
| format | article |
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In addition, the influence of reaction conditions on the polymerization yield was determined. The resulting polymer has been characterized by NMR, IR, gel permeation chromatography and differential scanning calorimetry. The glass transition temperature and melting point of the polydodecenamer are 19.6°C and 70.0°C respectively. Furthermore, cyclododecene has been polymerized into a low‐molecular‐weight polymer (12.0 × 103) with a polydispersity of 2.06 in high yields (94%). IR and NMR analysis indicate that the polydodecenamer has a high trans content (60%). Copyright © 2004 John Wiley & Sons, Ltd.</description><identifier>ISSN: 0268-2605</identifier><identifier>EISSN: 1099-0739</identifier><identifier>DOI: 10.1002/aoc.662</identifier><identifier>CODEN: AOCHEX</identifier><language>eng</language><publisher>Chichester, UK: John Wiley & Sons, Ltd</publisher><subject>Animal, plant and microbial ecology ; Applied ecology ; Biological and medical sciences ; catalyst ; Chemistry ; Condensed matter: structure, mechanical and thermal properties ; cyclododecene ; Ecotoxicology, biological effects of pollution ; electrochemistry ; Exact sciences and technology ; Fundamental and applied biological sciences. Psychology ; General aspects ; metathesis ; Organic chemistry ; Organometalloidal and organometallic compounds ; Physics ; polymerization ; Preparations and properties ; ROMP ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids ; WCl6</subject><ispartof>Applied organometallic chemistry, 2004-08, Vol.18 (8), p.375-379</ispartof><rights>Copyright © 2004 John Wiley & Sons, Ltd.</rights><rights>2004 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3272-a2a0a821ca035243515faa17666fb09c11ef5702607c62468dd00d9ff5a469ac3</citedby><cites>FETCH-LOGICAL-c3272-a2a0a821ca035243515faa17666fb09c11ef5702607c62468dd00d9ff5a469ac3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=16028044$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Karabulut, Solmaz</creatorcontrib><creatorcontrib>Çetinkaya, Sevil</creatorcontrib><creatorcontrib>Düz, Bülent</creatorcontrib><creatorcontrib>İmamoǧlu, Yavuz</creatorcontrib><title>Ring-opening metathesis polymerization of cyclododecene using an electrochemically reduced tungsten-based catalyst</title><title>Applied organometallic chemistry</title><addtitle>Appl. Organometal. Chem</addtitle><description>The ring‐opening metathesis polymerization of cyclododecene using an electrochemically reduced tungsten‐based catalyst (WCl6e−AlCH2Cl2) is described. In addition, the influence of reaction conditions on the polymerization yield was determined. The resulting polymer has been characterized by NMR, IR, gel permeation chromatography and differential scanning calorimetry. The glass transition temperature and melting point of the polydodecenamer are 19.6°C and 70.0°C respectively. Furthermore, cyclododecene has been polymerized into a low‐molecular‐weight polymer (12.0 × 103) with a polydispersity of 2.06 in high yields (94%). IR and NMR analysis indicate that the polydodecenamer has a high trans content (60%). Copyright © 2004 John Wiley & Sons, Ltd.</description><subject>Animal, plant and microbial ecology</subject><subject>Applied ecology</subject><subject>Biological and medical sciences</subject><subject>catalyst</subject><subject>Chemistry</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>cyclododecene</subject><subject>Ecotoxicology, biological effects of pollution</subject><subject>electrochemistry</subject><subject>Exact sciences and technology</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>General aspects</subject><subject>metathesis</subject><subject>Organic chemistry</subject><subject>Organometalloidal and organometallic compounds</subject><subject>Physics</subject><subject>polymerization</subject><subject>Preparations and properties</subject><subject>ROMP</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><subject>WCl6</subject><issn>0268-2605</issn><issn>1099-0739</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNp1kEtLxDAUhYMoOD7wL3QjLqTjTdqm06UMzij4AEfRXbimNxrtNEPSQeuvN1LRlavDhe8eOB9jBxzGHECcoNNjKcUGG3GoqhTKrNpkIxBykgoJxTbbCeEVACrJ8xHzt7Z9Tt2K2pjJkjrsXijYkKxc0y_J20_srGsTZxLd68bVriZNLSXr8P2AbUIN6c47_UJLq7Fp-sRTvdZUJ926fQ4dtekThnhq7LDpQ7fHtgw2gfZ_cpfdz87upufp5c38Ynp6mepMlCJFgYATwTVCVog8K3hhEHkppTRPUGnOyRRl3AWlliKXk7oGqCtjCsxlhTrbZUdDr_YuBE9Grbxdou8VB_WtSkVVKqqK5OFArjDECcZjq234wyWICeR55I4H7t021P9Xp05vpkNrOtA2Svj4pdG_KVlmZaEerudqsbi6yvnjTM2yL5UfiIs</recordid><startdate>200408</startdate><enddate>200408</enddate><creator>Karabulut, Solmaz</creator><creator>Çetinkaya, Sevil</creator><creator>Düz, Bülent</creator><creator>İmamoǧlu, Yavuz</creator><general>John Wiley & Sons, Ltd</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>200408</creationdate><title>Ring-opening metathesis polymerization of cyclododecene using an electrochemically reduced tungsten-based catalyst</title><author>Karabulut, Solmaz ; Çetinkaya, Sevil ; Düz, Bülent ; İmamoǧlu, Yavuz</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3272-a2a0a821ca035243515faa17666fb09c11ef5702607c62468dd00d9ff5a469ac3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Animal, plant and microbial ecology</topic><topic>Applied ecology</topic><topic>Biological and medical sciences</topic><topic>catalyst</topic><topic>Chemistry</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>cyclododecene</topic><topic>Ecotoxicology, biological effects of pollution</topic><topic>electrochemistry</topic><topic>Exact sciences and technology</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>General aspects</topic><topic>metathesis</topic><topic>Organic chemistry</topic><topic>Organometalloidal and organometallic compounds</topic><topic>Physics</topic><topic>polymerization</topic><topic>Preparations and properties</topic><topic>ROMP</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><topic>WCl6</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Karabulut, Solmaz</creatorcontrib><creatorcontrib>Çetinkaya, Sevil</creatorcontrib><creatorcontrib>Düz, Bülent</creatorcontrib><creatorcontrib>İmamoǧlu, Yavuz</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Applied organometallic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Karabulut, Solmaz</au><au>Çetinkaya, Sevil</au><au>Düz, Bülent</au><au>İmamoǧlu, Yavuz</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ring-opening metathesis polymerization of cyclododecene using an electrochemically reduced tungsten-based catalyst</atitle><jtitle>Applied organometallic chemistry</jtitle><addtitle>Appl. Organometal. Chem</addtitle><date>2004-08</date><risdate>2004</risdate><volume>18</volume><issue>8</issue><spage>375</spage><epage>379</epage><pages>375-379</pages><issn>0268-2605</issn><eissn>1099-0739</eissn><coden>AOCHEX</coden><abstract>The ring‐opening metathesis polymerization of cyclododecene using an electrochemically reduced tungsten‐based catalyst (WCl6e−AlCH2Cl2) is described. In addition, the influence of reaction conditions on the polymerization yield was determined. The resulting polymer has been characterized by NMR, IR, gel permeation chromatography and differential scanning calorimetry. The glass transition temperature and melting point of the polydodecenamer are 19.6°C and 70.0°C respectively. Furthermore, cyclododecene has been polymerized into a low‐molecular‐weight polymer (12.0 × 103) with a polydispersity of 2.06 in high yields (94%). IR and NMR analysis indicate that the polydodecenamer has a high trans content (60%). Copyright © 2004 John Wiley & Sons, Ltd.</abstract><cop>Chichester, UK</cop><pub>John Wiley & Sons, Ltd</pub><doi>10.1002/aoc.662</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0268-2605 |
| ispartof | Applied organometallic chemistry, 2004-08, Vol.18 (8), p.375-379 |
| issn | 0268-2605 1099-0739 |
| language | eng |
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| source | Wiley |
| subjects | Animal, plant and microbial ecology Applied ecology Biological and medical sciences catalyst Chemistry Condensed matter: structure, mechanical and thermal properties cyclododecene Ecotoxicology, biological effects of pollution electrochemistry Exact sciences and technology Fundamental and applied biological sciences. Psychology General aspects metathesis Organic chemistry Organometalloidal and organometallic compounds Physics polymerization Preparations and properties ROMP Structure of solids and liquids crystallography Structure of specific crystalline solids WCl6 |
| title | Ring-opening metathesis polymerization of cyclododecene using an electrochemically reduced tungsten-based catalyst |
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