Direct benzylation of carboxylic acids using Pd@Cu 2 (BDC) 2 DABCO via C‐H (sp 3 ) bond activation

In this study, Pd nanoparticles encapsulated in the copper‐based mesoporous metal–organic framework (Cu 2 (BDC) 2 DABCO) and used as a reusable heterogeneous catalyst to establish a method for the direct benzylation of carboxylic acids through C‐H (sp 3 ) bond activation. The catalyst structure was...

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Bibliographic Details
Published in:Applied organometallic chemistry 2024-09, Vol.38 (9)
Main Authors: Changizian, Zeynab Jafari, Mokhtari, Javad, Taheri, Salman
Format: Article
Language:English
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Summary:In this study, Pd nanoparticles encapsulated in the copper‐based mesoporous metal–organic framework (Cu 2 (BDC) 2 DABCO) and used as a reusable heterogeneous catalyst to establish a method for the direct benzylation of carboxylic acids through C‐H (sp 3 ) bond activation. The catalyst structure was characterized by scanning electron microscope (SEM), transmission electron microscopy (TEM), X‐ray diffraction (XRD), Brunauer–Emmett–Teller (BET), and inductively coupled plasma (ICP). This catalyst showed high catalytic activity, selectivity, and good functional group tolerance for the direct benzylation of carboxylic acids.
ISSN:0268-2605
1099-0739
DOI:10.1002/aoc.7627