Oil absorbents based on styrene-butadiene rubber

• Published in: Journal of applied polymer science 2003-08, Vol.89 (7), p.1818-1824
• Main Authors: Zhou, Mei Hua, Cho, Won-Jei
• Format: Article
• Language: English
• Subjects: Applied sciences; Exact sciences and technology; gel strength; Miscellaneous; oil absorbent; Organic polymers; Physicochemistry of polymers; Properties and characterization; styrene-butadiene rubber; swelling kinetic constant
• ISSN: 0021-8995; 1097-4628
• DOI: 10.1002/app.12252

Four oil absorbents based on styrene–butadiene (SBR)—pure SBR (PS), 4‐tert‐butylstyrene–SBR (PBS), EPDM–SBR network (PES), and 4‐tert‐butylstyrene‐EPDM‐SBR (PBES)—were produced from crosslinking polymerization of uncured styrene–butadiene rubber (SBR), 4‐tert‐butylstyrene (tBS), and ethylene–propylene–diene terpolymer (EPDM). The reaction took place in toluene using benzoyl peroxide (BPO) as an initiator. Uncured SBR was used as both a prepolymer and a crosslink agent in this work, and the crosslinked polymer was identified by IR spectroscopy. The oil absorbency of the crosslinked polymer was evaluated with ASTM method F726‐81. The order of maximum oil absorbency was PBES > PBS > PES > PS. The maximum values of oil absorbency of PBES and PBS were 74.0 and 69.5 g/g, respectively. Gel fractions and swelling kinetic constants, however, had opposite sequences. The swelling kinetic constant of PS evaluated by an experimental equation was 49.97 × 10−2 h−1. The gel strength parameter, S, the relaxation exponent, n, and the fractal dimension, df, of the crosslinked polymer at the pseudo‐critical gel state were determined from oscillatory shear measurements by a dynamic rheometer. The morphologies and light resistance properties of the crosslinked polymers were observed, respectively, with a scanning electron microscope (SEM) and a color difference meter.