Thermodynamics of creep rupture

An earlier discussion of the entropy contributions to the well‐known Zhurkov relationship for creep rupture is developed from a more rigorous basis. It is demonstrated that well‐behaved Zhurkov materials (which follow his relationship closely) undergo quasistatic rupture (thermodynamically reversibl...

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Published in:Journal of applied polymer science 1984-05, Vol.29 (5), p.1547-1551
Main Author: Papazian, Harold A.
Format: Article
Language:English
Subjects:
Applied sciences
Exact sciences and technology
Mechanical properties
Physical properties
Polymer industry, paints, wood
Properties and testing
Technology of polymers
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description An earlier discussion of the entropy contributions to the well‐known Zhurkov relationship for creep rupture is developed from a more rigorous basis. It is demonstrated that well‐behaved Zhurkov materials (which follow his relationship closely) undergo quasistatic rupture (thermodynamically reversible). Other materials show modified Zhurkov behavior and can be described as undergoing nonquasistatic rupture, with an extra entropy term. By considering studies previously carried out in vacuum, this extra entropy has been attributed to surface phenomena.
doi_str_mv 10.1002/app.1984.070290509
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source Wiley Online Library Polymer Backfiles; Wiley-Blackwell Journals (Backfile Content)
subjects Applied sciences
Exact sciences and technology
Mechanical properties
Physical properties
Polymer industry, paints, wood
Properties and testing
Technology of polymers
title Thermodynamics of creep rupture
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