Polyurethane-urea anionomer dispersions. I

Polyurethane–urea anionomer dispersions with different stoichiometric DMPA/polyol and NCO/OH ratios were preapred from poly(oxypropylene)glycol, toluene diisocyanate (TDI), dimethylolpropionic acid (DMPA), and ethylenediamine (EDA). The dispersion‐cast films were prepared and characterized by mechan...

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Bibliographic Details
Published in:Journal of applied polymer science 1994-12, Vol.54 (11), p.1643-1650
Main Authors: Xiao, Hong, Xiao, Han X., Frisch, Kurt C., Malwitz, Nelson
Format: Article
Language:English
Subjects:
Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polycondensation
Preparation, kinetics, thermodynamics, mechanism and catalysts
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Summary:Polyurethane–urea anionomer dispersions with different stoichiometric DMPA/polyol and NCO/OH ratios were preapred from poly(oxypropylene)glycol, toluene diisocyanate (TDI), dimethylolpropionic acid (DMPA), and ethylenediamine (EDA). The dispersion‐cast films were prepared and characterized by mechanical properties, dynamic mechanical analysis (DMA), and differential scanning calorimetry (DSC). Increasing the hard‐segment content by either increasing the DMPA/polyol or the NCO/OH ratios affects the glass transition temperature (Tg) of the soft segments. © 1994 John Wiley & Sons, Inc.
ISSN:0021-8995
1097-4628
DOI:10.1002/app.1994.070541107