Cocrystallization of Imide-Fused Corannulene Derivatives and C 60 : Guest-Induced Conformational Switching and 1:1 Segregated Packing

A pair of interconvertible stereoisomers of imide-fused corannulene derivatives was mixed with C , which resulted in cocrystallization into a 1:1 segregated packing motif through concave-convex π-π interactions. Only one conformation was observed in the cocrystal owing to guest-induced conformationa...

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Bibliographic Details
Published in:Chemistry, an Asian journal an Asian journal, 2018-10, Vol.13 (19), p.2934-2938
Main Authors: Lu, Ru-Qiang, Wu, Shuang, Bao, Yue-Hua, Yang, Lin-Lin, Qu, Hang, Saha, Mithu, Wang, Xiao-Ye, Zhuo, You-Zhen, Xu, Binbin, Pei, Jian, Zhang, Hui, Weng, Wengui, Cao, Xiao-Yu
Format: Article
Language:English
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Summary:A pair of interconvertible stereoisomers of imide-fused corannulene derivatives was mixed with C , which resulted in cocrystallization into a 1:1 segregated packing motif through concave-convex π-π interactions. Only one conformation was observed in the cocrystal owing to guest-induced conformational switching. The 1D assemblies of the complex showed promising applications in organic electronics.
ISSN:1861-4728
1861-471X
DOI:10.1002/asia.201801086