Front Cover: Controlling the Emergence and Shift Direction of Mechanochromic Luminescence Color of a Pyridine‐Terminated Compound (Chem. Asian J. 3/2019)

A pyridine‐terminated fluorescent luminophore has been synthesized that exhibited mechanochromic luminescence (MCL) when combined with an acid. Although the luminophore showed both blue and red shifts in the photoluminescence spectra upon mechanical grinding with different acid species, it exhibited...

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Bibliographic Details
Published in:Chemistry, an Asian journal an Asian journal, 2019-02, Vol.14 (3), p.328-328
Main Authors: Kondo, Mizuho, Yamoto, Taku, Miura, Seiya, Hashimoto, Mayuko, Kitamura, Chitoshi, Kawatsuki, Nobuhiro
Format: Article
Language:English
Subjects:
aggregation
conjugation
luminescence
supramolecular chemistry
Online Access:Get full text
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Summary:A pyridine‐terminated fluorescent luminophore has been synthesized that exhibited mechanochromic luminescence (MCL) when combined with an acid. Although the luminophore showed both blue and red shifts in the photoluminescence spectra upon mechanical grinding with different acid species, it exhibited little mechanoresponsiveness itself. Furthermore, compounds with similar molecular backbones to the dye/acid complex were synthesized to clarify the color‐change mechanism. The compounds showed both blue and red shifts in the photoluminescence spectra and diffuse reflectance spectra upon grinding, indicating that the aggregation structure plays an important role in the mechanoresponsive behavior rather than the π‐conjugated structure. More information can be found in the Full Paper by Mizuho Kondo, Nobuhiro Kawatsuki et al. on page 471 in Issue 3, 2019 (DOI: 10.1002/asia.201801647).
ISSN:1861-4728
1861-471X
DOI:10.1002/asia.201900038