Coordination Flexibility Aided CO 2 -specific Gating in an Iron Isonicotinate MOF

• Published in: Chemistry, an Asian journal an Asian journal, 2022-02, Vol.17 (4), p.e202101305
• Main Authors: Singh, Himan Dev, Nandi, Shyamapada, Chakraborty, Debanjan, Singh, Kirandeep, Vinod, Chathakudath P, Vaidhyanathan, Ramanathan
• Format: Article
• Language: English
• ISSN: 1861-4728; 1861-471X
• DOI: 10.1002/asia.202101305

Coordination flexibility assisted porosity has been introduced into an Iron-isonicotinate metal-organic framework (MOF), (Fe(4-PyC)  ⋅ (OH). The framework showed CO -specific gate opening behavior, which gets tuned as a function of temperature and pressure. The MOF's physisorptive porosity towards CO , CH , and N was investigated; it adsorbed only CO via a gate opening phenomenon. The isonicotinate, representing a borderline soft base, is bound to the hard Fe centre through monodentate carboxylate and pyridyl nitrogen. This moderately weak binding enables isonicotinate to spin like a spindle under the CO pressure opening the gate for a sharp increase in CO uptake at 333 mmHg (At 298 K, the CO uptake increases from 0.70 to 1.57 mmol/g). We investigated the MOF's potential for CO /N and CO /CH gas separation aided by this gating. IAST model reveals that the CO /N selectivity jumps from 325 to 3131 when the gate opens, while the CO /CH selectivity increases three times. Interestingly, this Fe-isonicotinate MOF did not follow the trend set by our earlier reported Hard-Soft Gate Control (established for isostructural M -isonicotinate MOFs (M=Mg, Mn)). However, we account for this discrepancy using the different oxidation state of metals confirmed by X-ray photoelectron spectroscopy and magnetism.