Oxygen Vacancies of Commercial V 2 O 5 Induced by Mechanical Force to Enhance the Diffusion of Zinc Ions in Aqueous Zinc Battery

• Published in: Batteries & supercaps 2022-04, Vol.5 (4)
• Main Authors: Zhao, Danyang, Zhu, Qiancheng, Li, Xiaohui, Dun, Menghan, Wang, Yin, Huang, Xintang
• Format: Article
• Language: English
• ISSN: 2566-6223; 2566-6223
• DOI: 10.1002/batt.202100341

Rechargeable aqueous batteries with Zn 2+ as a media‐ion are promising candidates for large‐scale energy storage because of their intrinsic safety, low‐cost and high energy‐intensity. Vanadium based cathodic materials have gained significant attention in aqueous zinc‐ion batteries (AZIBs) due to their high capacity and satisfactory cycle stability. However, more facile and efficient fabrication methods should be explored when considering future realistic application. Herein, commercial V 2 O 5 cathodes with oxygen vacancies were fabricated through a simple mechanical ball milling method. The results suggest that mechanical force can directly induce the oxygen vacancies in commercial V 2 O 5 , which significantly enhance the diffusion of Zn ions. The oxygen vacancy−V 2 O 5 (O v −V 2 O 5 ) shows much higher capacity than the pristine commercial V 2 O 5 and the cyclic stability reached 2500 times. O v −V 2 O 5 cathode with a facile synthesis technology is a promising candidate for future high‐performance, low‐cost, safe, and environment‐friendly Zn battery devices.