In situ Polymerized FDU‐12/Poly(methyl methacrylate) and FDU‐12/polyamide 6 Nanocomposites for Cd 2+ Adsorption

Large‐pore mesoporous silica FDU‐12 was synthesized and functionalized with silane coupling agents bearing methacrylate and diamino groups. Diamino‐functionalized FDU‐12/polyamide 6 and methacrylate‐functionalized FDU‐12/poly(methyl methacrylate) nanocomposites were prepared via in situ polymerizati...

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Published in:Chemical engineering & technology 2021-03, Vol.44 (3), p.431-440
Main Authors: Zabihi, Samyar, Jamshidian, Sahar, Soltani, Roozbeh, Pelalak, Rasool, Heidari, Zahra, Marjani, Azam, Ghadiri, Mahdi
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description Large‐pore mesoporous silica FDU‐12 was synthesized and functionalized with silane coupling agents bearing methacrylate and diamino groups. Diamino‐functionalized FDU‐12/polyamide 6 and methacrylate‐functionalized FDU‐12/poly(methyl methacrylate) nanocomposites were prepared via in situ polymerization approach. These two synthesized nanocomposites were used as potential adsorbents for the removal of Cd 2+ cations from aqueous media. The impact of different adsorption factors affecting the adsorption process was investigated, and isotherm and kinetic studies were conducted to gain a better understanding of adsorption mechanisms involved in the removal process of Cd 2+ by the adsorbents. Experimental and computational results demonstrated that the adsorbents have acceptable performance for Cd 2+ uptake.
doi_str_mv 10.1002/ceat.202000298
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title In situ Polymerized FDU‐12/Poly(methyl methacrylate) and FDU‐12/polyamide 6 Nanocomposites for Cd 2+ Adsorption
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