Cover Picture: Reaction Chemistry of Complexes Containing PtH, PtSH, or PtS Fragments: From Their Apparent Simplicity to the Maze of Reactions Underlying Their Interconversion (Chem. Eur. J. 4/2007)

A labyrinth mimicking the reaction pathways that govern the interconversion of complexes containing PtH, PtSH, and PtS fragments is depicted on the cover. The network of reactions has been established by the addition of controlled amounts of Na 2 S or NaHS to the binuclear trihydride complex [Pt...

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Bibliographic Details
Published in:Chemistry : a European journal 2007-01, Vol.13 (4), p.1011-1011
Main Authors: Novio, Fernando, González-Duarte, Pilar, Lledós, Agustí, Mas-Ballesté, Rubén
Format: Article
Language:English
Subjects:
hydride ligands
phosphane ligands
platinum
S ligands
structure elucidation
Online Access:Get full text
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Summary:A labyrinth mimicking the reaction pathways that govern the interconversion of complexes containing PtH, PtSH, and PtS fragments is depicted on the cover. The network of reactions has been established by the addition of controlled amounts of Na 2 S or NaHS to the binuclear trihydride complex [Pt 2 (H) 2 (μ‐H)(dppp) 2 ]ClO 4 (dppp=1,3‐bis(diphenylphosphanyl)propane) and by subsequent treatment of the resulting species with protons, hydride, hydroxide, or hydrogen sulfide ions. Further details are provided in the article by P. González‐Duarte, A. Lledós et al. on page 1047 ff.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.200790011