Loading…
A Series of Trifacial Pd 6 Molecular Barrels with Porphyrin Walls
Three new nanoscopic trigonal prisms, [(tmen) 6 Pd 6 (H 2 L) 3 ](NO 3 ) 12 ( 1 ), [(Meen) 6 Pd 6 (H 2 L) 3 ](NO 3 ) 12 ( 2 ), and [(2,2′‐bipy) 6 Pd 6 (H 2 L) 3 ](NO 3 ) 12 ( 3 ), have been synthesized in excellent yields through single‐step metal–ligand‐coordination‐driven self‐assembly using 5,10,1...
Saved in:
| Published in: | Chemistry : a European journal 2012-07, Vol.18 (31), p.9571-9579 |
|---|---|
| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c154t-c0fdcce2f1df4a6830e7d41bb4d5205d936ad60ab16fa403188699d94711c0213 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c154t-c0fdcce2f1df4a6830e7d41bb4d5205d936ad60ab16fa403188699d94711c0213 |
| container_end_page | 9579 |
| container_issue | 31 |
| container_start_page | 9571 |
| container_title | Chemistry : a European journal |
| container_volume | 18 |
| creator | Bar, Arun Kumar Mohapatra, Sudip Zangrando, Ennio Mukherjee, Partha Sarathi |
| description | Three new nanoscopic trigonal prisms, [(tmen)
6
Pd
6
(H
2
L)
3
](NO
3
)
12
(
1
), [(Meen)
6
Pd
6
(H
2
L)
3
](NO
3
)
12
(
2
), and [(2,2′‐bipy)
6
Pd
6
(H
2
L)
3
](NO
3
)
12
(
3
), have been synthesized in excellent yields through single‐step metal–ligand‐coordination‐driven self‐assembly using 5,10,15,20‐tetrakis(3‐pyridyl)porphyrin (H
2
L) as a donor and
cis
‐blocked Pd
II
90° acceptors. These complexes were fully characterized by spectroscopic studies and single‐crystal X‐ray diffraction. All of these barrels quantitatively bind Zn
II
ions in the N
4
pockets of the porphyrin walls at room temperature. Their corresponding zinc‐embedded complexes, [(tmen)
6
Pd
6
(ZnL)
3
](NO
3
)
12
(
1 a
), [(Meen)
6
Pd
6
(ZnL)
3
](NO
3
)
12
(
2 a
), and [(2,2′‐bipy)
6
Pd
6
(ZnL)
3
](NO
3
)
12
(
3 a
), were synthesized under ambient conditions by the post‐synthetic binding of Zn
II
ions into the H
2
N
4
pockets of the porphyrin walls of these complexes. These zinc‐embedded complexes were characterized by electronic absorption, fluorescence emission,
1
H NMR spectroscopy, as well as elemental analysis. Complexes
1
–
3
exhibited considerable microporosity in their solid state. Complex
1
was an efficient adsorbent for nitrogen gas and EtOH, MeOH, and water vapors. |
| doi_str_mv | 10.1002/chem.201201077 |
| format | article |
| fullrecord | <record><control><sourceid>crossref</sourceid><recordid>TN_cdi_crossref_primary_10_1002_chem_201201077</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1002_chem_201201077</sourcerecordid><originalsourceid>FETCH-LOGICAL-c154t-c0fdcce2f1df4a6830e7d41bb4d5205d936ad60ab16fa403188699d94711c0213</originalsourceid><addsrcrecordid>eNo90EtLAzEUBeAgCtbq1nX-wIz35jWT5Vh8QcWCFZdDJg8mkjolqUj_vS2KcODsDoePkGuEGgHYjR39pmaAh0DTnJAZSoYVb5Q8JTPQoqmU5PqcXJTyAQBacT4jXUdffY6-0CnQdY7B2GgSXTmq6POUvP1KJtNbk7NPhX7H3UhXU96O-xw_6btJqVySs2BS8Vd_PSdv93frxWO1fHl4WnTLyqIUu8pCcNZ6FtAFYVTLwTdO4DAIJxlIp7kyToEZUAUjgGPbKq3d4TaiBYZ8TurfXZunUrIP_TbHjcn7HqE_AvRHgP4fgP8A9cxNjQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>A Series of Trifacial Pd 6 Molecular Barrels with Porphyrin Walls</title><source>Wiley-Blackwell Read & Publish Collection</source><creator>Bar, Arun Kumar ; Mohapatra, Sudip ; Zangrando, Ennio ; Mukherjee, Partha Sarathi</creator><creatorcontrib>Bar, Arun Kumar ; Mohapatra, Sudip ; Zangrando, Ennio ; Mukherjee, Partha Sarathi</creatorcontrib><description>Three new nanoscopic trigonal prisms, [(tmen)
6
Pd
6
(H
2
L)
3
](NO
3
)
12
(
1
), [(Meen)
6
Pd
6
(H
2
L)
3
](NO
3
)
12
(
2
), and [(2,2′‐bipy)
6
Pd
6
(H
2
L)
3
](NO
3
)
12
(
3
), have been synthesized in excellent yields through single‐step metal–ligand‐coordination‐driven self‐assembly using 5,10,15,20‐tetrakis(3‐pyridyl)porphyrin (H
2
L) as a donor and
cis
‐blocked Pd
II
90° acceptors. These complexes were fully characterized by spectroscopic studies and single‐crystal X‐ray diffraction. All of these barrels quantitatively bind Zn
II
ions in the N
4
pockets of the porphyrin walls at room temperature. Their corresponding zinc‐embedded complexes, [(tmen)
6
Pd
6
(ZnL)
3
](NO
3
)
12
(
1 a
), [(Meen)
6
Pd
6
(ZnL)
3
](NO
3
)
12
(
2 a
), and [(2,2′‐bipy)
6
Pd
6
(ZnL)
3
](NO
3
)
12
(
3 a
), were synthesized under ambient conditions by the post‐synthetic binding of Zn
II
ions into the H
2
N
4
pockets of the porphyrin walls of these complexes. These zinc‐embedded complexes were characterized by electronic absorption, fluorescence emission,
1
H NMR spectroscopy, as well as elemental analysis. Complexes
1
–
3
exhibited considerable microporosity in their solid state. Complex
1
was an efficient adsorbent for nitrogen gas and EtOH, MeOH, and water vapors.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201201077</identifier><language>eng</language><ispartof>Chemistry : a European journal, 2012-07, Vol.18 (31), p.9571-9579</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c154t-c0fdcce2f1df4a6830e7d41bb4d5205d936ad60ab16fa403188699d94711c0213</citedby><cites>FETCH-LOGICAL-c154t-c0fdcce2f1df4a6830e7d41bb4d5205d936ad60ab16fa403188699d94711c0213</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Bar, Arun Kumar</creatorcontrib><creatorcontrib>Mohapatra, Sudip</creatorcontrib><creatorcontrib>Zangrando, Ennio</creatorcontrib><creatorcontrib>Mukherjee, Partha Sarathi</creatorcontrib><title>A Series of Trifacial Pd 6 Molecular Barrels with Porphyrin Walls</title><title>Chemistry : a European journal</title><description>Three new nanoscopic trigonal prisms, [(tmen)
6
Pd
6
(H
2
L)
3
](NO
3
)
12
(
1
), [(Meen)
6
Pd
6
(H
2
L)
3
](NO
3
)
12
(
2
), and [(2,2′‐bipy)
6
Pd
6
(H
2
L)
3
](NO
3
)
12
(
3
), have been synthesized in excellent yields through single‐step metal–ligand‐coordination‐driven self‐assembly using 5,10,15,20‐tetrakis(3‐pyridyl)porphyrin (H
2
L) as a donor and
cis
‐blocked Pd
II
90° acceptors. These complexes were fully characterized by spectroscopic studies and single‐crystal X‐ray diffraction. All of these barrels quantitatively bind Zn
II
ions in the N
4
pockets of the porphyrin walls at room temperature. Their corresponding zinc‐embedded complexes, [(tmen)
6
Pd
6
(ZnL)
3
](NO
3
)
12
(
1 a
), [(Meen)
6
Pd
6
(ZnL)
3
](NO
3
)
12
(
2 a
), and [(2,2′‐bipy)
6
Pd
6
(ZnL)
3
](NO
3
)
12
(
3 a
), were synthesized under ambient conditions by the post‐synthetic binding of Zn
II
ions into the H
2
N
4
pockets of the porphyrin walls of these complexes. These zinc‐embedded complexes were characterized by electronic absorption, fluorescence emission,
1
H NMR spectroscopy, as well as elemental analysis. Complexes
1
–
3
exhibited considerable microporosity in their solid state. Complex
1
was an efficient adsorbent for nitrogen gas and EtOH, MeOH, and water vapors.</description><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNo90EtLAzEUBeAgCtbq1nX-wIz35jWT5Vh8QcWCFZdDJg8mkjolqUj_vS2KcODsDoePkGuEGgHYjR39pmaAh0DTnJAZSoYVb5Q8JTPQoqmU5PqcXJTyAQBacT4jXUdffY6-0CnQdY7B2GgSXTmq6POUvP1KJtNbk7NPhX7H3UhXU96O-xw_6btJqVySs2BS8Vd_PSdv93frxWO1fHl4WnTLyqIUu8pCcNZ6FtAFYVTLwTdO4DAIJxlIp7kyToEZUAUjgGPbKq3d4TaiBYZ8TurfXZunUrIP_TbHjcn7HqE_AvRHgP4fgP8A9cxNjQ</recordid><startdate>20120727</startdate><enddate>20120727</enddate><creator>Bar, Arun Kumar</creator><creator>Mohapatra, Sudip</creator><creator>Zangrando, Ennio</creator><creator>Mukherjee, Partha Sarathi</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20120727</creationdate><title>A Series of Trifacial Pd 6 Molecular Barrels with Porphyrin Walls</title><author>Bar, Arun Kumar ; Mohapatra, Sudip ; Zangrando, Ennio ; Mukherjee, Partha Sarathi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c154t-c0fdcce2f1df4a6830e7d41bb4d5205d936ad60ab16fa403188699d94711c0213</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bar, Arun Kumar</creatorcontrib><creatorcontrib>Mohapatra, Sudip</creatorcontrib><creatorcontrib>Zangrando, Ennio</creatorcontrib><creatorcontrib>Mukherjee, Partha Sarathi</creatorcontrib><collection>CrossRef</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bar, Arun Kumar</au><au>Mohapatra, Sudip</au><au>Zangrando, Ennio</au><au>Mukherjee, Partha Sarathi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Series of Trifacial Pd 6 Molecular Barrels with Porphyrin Walls</atitle><jtitle>Chemistry : a European journal</jtitle><date>2012-07-27</date><risdate>2012</risdate><volume>18</volume><issue>31</issue><spage>9571</spage><epage>9579</epage><pages>9571-9579</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><abstract>Three new nanoscopic trigonal prisms, [(tmen)
6
Pd
6
(H
2
L)
3
](NO
3
)
12
(
1
), [(Meen)
6
Pd
6
(H
2
L)
3
](NO
3
)
12
(
2
), and [(2,2′‐bipy)
6
Pd
6
(H
2
L)
3
](NO
3
)
12
(
3
), have been synthesized in excellent yields through single‐step metal–ligand‐coordination‐driven self‐assembly using 5,10,15,20‐tetrakis(3‐pyridyl)porphyrin (H
2
L) as a donor and
cis
‐blocked Pd
II
90° acceptors. These complexes were fully characterized by spectroscopic studies and single‐crystal X‐ray diffraction. All of these barrels quantitatively bind Zn
II
ions in the N
4
pockets of the porphyrin walls at room temperature. Their corresponding zinc‐embedded complexes, [(tmen)
6
Pd
6
(ZnL)
3
](NO
3
)
12
(
1 a
), [(Meen)
6
Pd
6
(ZnL)
3
](NO
3
)
12
(
2 a
), and [(2,2′‐bipy)
6
Pd
6
(ZnL)
3
](NO
3
)
12
(
3 a
), were synthesized under ambient conditions by the post‐synthetic binding of Zn
II
ions into the H
2
N
4
pockets of the porphyrin walls of these complexes. These zinc‐embedded complexes were characterized by electronic absorption, fluorescence emission,
1
H NMR spectroscopy, as well as elemental analysis. Complexes
1
–
3
exhibited considerable microporosity in their solid state. Complex
1
was an efficient adsorbent for nitrogen gas and EtOH, MeOH, and water vapors.</abstract><doi>10.1002/chem.201201077</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0947-6539 |
| ispartof | Chemistry : a European journal, 2012-07, Vol.18 (31), p.9571-9579 |
| issn | 0947-6539 1521-3765 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_chem_201201077 |
| source | Wiley-Blackwell Read & Publish Collection |
| title | A Series of Trifacial Pd 6 Molecular Barrels with Porphyrin Walls |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-12T20%3A06%3A55IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20Series%20of%20Trifacial%20Pd%206%20Molecular%20Barrels%20with%20Porphyrin%20Walls&rft.jtitle=Chemistry%20:%20a%20European%20journal&rft.au=Bar,%20Arun%20Kumar&rft.date=2012-07-27&rft.volume=18&rft.issue=31&rft.spage=9571&rft.epage=9579&rft.pages=9571-9579&rft.issn=0947-6539&rft.eissn=1521-3765&rft_id=info:doi/10.1002/chem.201201077&rft_dat=%3Ccrossref%3E10_1002_chem_201201077%3C/crossref%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c154t-c0fdcce2f1df4a6830e7d41bb4d5205d936ad60ab16fa403188699d94711c0213%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |