Loading…

Cover Feature: Absolute Configuration Assignment from Optical Rotation Data by Means of Biphenyl Chiroptical Probes (Chem. Eur. J. 22/2019)

A central‐to‐axial chirality transfer occurring when chiral molecules are linked to flexible biphenyl probes makes it possible to assign their absolute configuration from the biphenyl twist. By employing 4,4’‐disubstituted biphenyls, the twist sign, and then the absolute configuration, can be reveal...

Full description

Saved in:
Bibliographic Details
Published in:Chemistry : a European journal 2019-04, Vol.25 (22), p.5597-5597
Main Authors: Vergura, Stefania, Scafato, Patrizia, Belviso, Sandra, Superchi, Stefano
Format: Article
Language:English
Subjects:
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page 5597
container_issue 22
container_start_page 5597
container_title Chemistry : a European journal
container_volume 25
creator Vergura, Stefania
Scafato, Patrizia
Belviso, Sandra
Superchi, Stefano
description A central‐to‐axial chirality transfer occurring when chiral molecules are linked to flexible biphenyl probes makes it possible to assign their absolute configuration from the biphenyl twist. By employing 4,4’‐disubstituted biphenyls, the twist sign, and then the absolute configuration, can be revealed by the sign of optical rotation. This allows for assignment of the absolute configuration of chiral α‐substituted carboxylic acids and primary amines in a non‐empirical and straightforward way by simple [α]D measurements. More information can be found in the Full Paper by S. Superchi et al. on page 5682.
doi_str_mv 10.1002/chem.201901165
format article
fullrecord <record><control><sourceid>wiley_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1002_chem_201901165</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>CHEM201901165</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1295-9d3327fc8633fe51ee8db07d862e16446d456814b4d2e9764cfbd19dee0475113</originalsourceid><addsrcrecordid>eNqFkLFOwzAURS0EEqWwMnuEIantOE7MVkJLQa2KEMyRkzy3QUlc2Qko38BP06gVjExvOefqvovQNSU-JYRN8i3UPiNUEkpFeIJGNGTUCyIRnqIRkTzyRBjIc3Th3AchRIogGKHvxHyCxXNQbWfhDk8zZ6quBZyYRpebzqq2NA2eOldumhqaFmtrarzetWWuKvxq2gPwoFqFsx6vQDUOG43vy90Wmr7Cyba05oi_WJOBwzfJUBXPOuvjZx8zNhlq316iM60qB1fHO0bv89lbsvCW68enZLr0cspk6MkiCFik83j_gIaQAsRFRqIiFgyo4FwUPBQx5RkvGMhI8FxnBZUFAOFRSGkwRv4hN7fGOQs63dmyVrZPKUmHKdNhyvR3yr0gD8JXWUH_D50mi9nqz_0BjJZ3Sg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Cover Feature: Absolute Configuration Assignment from Optical Rotation Data by Means of Biphenyl Chiroptical Probes (Chem. Eur. J. 22/2019)</title><source>Wiley-Blackwell Read &amp; Publish Collection</source><creator>Vergura, Stefania ; Scafato, Patrizia ; Belviso, Sandra ; Superchi, Stefano</creator><creatorcontrib>Vergura, Stefania ; Scafato, Patrizia ; Belviso, Sandra ; Superchi, Stefano</creatorcontrib><description>A central‐to‐axial chirality transfer occurring when chiral molecules are linked to flexible biphenyl probes makes it possible to assign their absolute configuration from the biphenyl twist. By employing 4,4’‐disubstituted biphenyls, the twist sign, and then the absolute configuration, can be revealed by the sign of optical rotation. This allows for assignment of the absolute configuration of chiral α‐substituted carboxylic acids and primary amines in a non‐empirical and straightforward way by simple [α]D measurements. More information can be found in the Full Paper by S. Superchi et al. on page 5682.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201901165</identifier><language>eng</language><subject>absolute configuration ; biphenyls ; chiroptical probes ; circular dichroism ; optical rotation</subject><ispartof>Chemistry : a European journal, 2019-04, Vol.25 (22), p.5597-5597</ispartof><rights>2019 Wiley‐VCH Verlag GmbH &amp; Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0002-6301-2856 ; 0000-0002-7265-1625 ; 0000-0002-2997-0129 ; 0000-0003-4101-8541</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Vergura, Stefania</creatorcontrib><creatorcontrib>Scafato, Patrizia</creatorcontrib><creatorcontrib>Belviso, Sandra</creatorcontrib><creatorcontrib>Superchi, Stefano</creatorcontrib><title>Cover Feature: Absolute Configuration Assignment from Optical Rotation Data by Means of Biphenyl Chiroptical Probes (Chem. Eur. J. 22/2019)</title><title>Chemistry : a European journal</title><description>A central‐to‐axial chirality transfer occurring when chiral molecules are linked to flexible biphenyl probes makes it possible to assign their absolute configuration from the biphenyl twist. By employing 4,4’‐disubstituted biphenyls, the twist sign, and then the absolute configuration, can be revealed by the sign of optical rotation. This allows for assignment of the absolute configuration of chiral α‐substituted carboxylic acids and primary amines in a non‐empirical and straightforward way by simple [α]D measurements. More information can be found in the Full Paper by S. Superchi et al. on page 5682.</description><subject>absolute configuration</subject><subject>biphenyls</subject><subject>chiroptical probes</subject><subject>circular dichroism</subject><subject>optical rotation</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqFkLFOwzAURS0EEqWwMnuEIantOE7MVkJLQa2KEMyRkzy3QUlc2Qko38BP06gVjExvOefqvovQNSU-JYRN8i3UPiNUEkpFeIJGNGTUCyIRnqIRkTzyRBjIc3Th3AchRIogGKHvxHyCxXNQbWfhDk8zZ6quBZyYRpebzqq2NA2eOldumhqaFmtrarzetWWuKvxq2gPwoFqFsx6vQDUOG43vy90Wmr7Cyba05oi_WJOBwzfJUBXPOuvjZx8zNhlq316iM60qB1fHO0bv89lbsvCW68enZLr0cspk6MkiCFik83j_gIaQAsRFRqIiFgyo4FwUPBQx5RkvGMhI8FxnBZUFAOFRSGkwRv4hN7fGOQs63dmyVrZPKUmHKdNhyvR3yr0gD8JXWUH_D50mi9nqz_0BjJZ3Sg</recordid><startdate>20190417</startdate><enddate>20190417</enddate><creator>Vergura, Stefania</creator><creator>Scafato, Patrizia</creator><creator>Belviso, Sandra</creator><creator>Superchi, Stefano</creator><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-6301-2856</orcidid><orcidid>https://orcid.org/0000-0002-7265-1625</orcidid><orcidid>https://orcid.org/0000-0002-2997-0129</orcidid><orcidid>https://orcid.org/0000-0003-4101-8541</orcidid></search><sort><creationdate>20190417</creationdate><title>Cover Feature: Absolute Configuration Assignment from Optical Rotation Data by Means of Biphenyl Chiroptical Probes (Chem. Eur. J. 22/2019)</title><author>Vergura, Stefania ; Scafato, Patrizia ; Belviso, Sandra ; Superchi, Stefano</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1295-9d3327fc8633fe51ee8db07d862e16446d456814b4d2e9764cfbd19dee0475113</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>absolute configuration</topic><topic>biphenyls</topic><topic>chiroptical probes</topic><topic>circular dichroism</topic><topic>optical rotation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Vergura, Stefania</creatorcontrib><creatorcontrib>Scafato, Patrizia</creatorcontrib><creatorcontrib>Belviso, Sandra</creatorcontrib><creatorcontrib>Superchi, Stefano</creatorcontrib><collection>CrossRef</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Vergura, Stefania</au><au>Scafato, Patrizia</au><au>Belviso, Sandra</au><au>Superchi, Stefano</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Cover Feature: Absolute Configuration Assignment from Optical Rotation Data by Means of Biphenyl Chiroptical Probes (Chem. Eur. J. 22/2019)</atitle><jtitle>Chemistry : a European journal</jtitle><date>2019-04-17</date><risdate>2019</risdate><volume>25</volume><issue>22</issue><spage>5597</spage><epage>5597</epage><pages>5597-5597</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><abstract>A central‐to‐axial chirality transfer occurring when chiral molecules are linked to flexible biphenyl probes makes it possible to assign their absolute configuration from the biphenyl twist. By employing 4,4’‐disubstituted biphenyls, the twist sign, and then the absolute configuration, can be revealed by the sign of optical rotation. This allows for assignment of the absolute configuration of chiral α‐substituted carboxylic acids and primary amines in a non‐empirical and straightforward way by simple [α]D measurements. More information can be found in the Full Paper by S. Superchi et al. on page 5682.</abstract><doi>10.1002/chem.201901165</doi><tpages>1</tpages><orcidid>https://orcid.org/0000-0002-6301-2856</orcidid><orcidid>https://orcid.org/0000-0002-7265-1625</orcidid><orcidid>https://orcid.org/0000-0002-2997-0129</orcidid><orcidid>https://orcid.org/0000-0003-4101-8541</orcidid><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 0947-6539
ispartof Chemistry : a European journal, 2019-04, Vol.25 (22), p.5597-5597
issn 0947-6539
1521-3765
language eng
recordid cdi_crossref_primary_10_1002_chem_201901165
source Wiley-Blackwell Read & Publish Collection
subjects absolute configuration
biphenyls
chiroptical probes
circular dichroism
optical rotation
title Cover Feature: Absolute Configuration Assignment from Optical Rotation Data by Means of Biphenyl Chiroptical Probes (Chem. Eur. J. 22/2019)
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T11%3A59%3A39IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-wiley_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Cover%20Feature:%20Absolute%20Configuration%20Assignment%20from%20Optical%20Rotation%20Data%20by%20Means%20of%20Biphenyl%20Chiroptical%20Probes%20(Chem.%20Eur.%20J.%2022/2019)&rft.jtitle=Chemistry%20:%20a%20European%20journal&rft.au=Vergura,%20Stefania&rft.date=2019-04-17&rft.volume=25&rft.issue=22&rft.spage=5597&rft.epage=5597&rft.pages=5597-5597&rft.issn=0947-6539&rft.eissn=1521-3765&rft_id=info:doi/10.1002/chem.201901165&rft_dat=%3Cwiley_cross%3ECHEM201901165%3C/wiley_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c1295-9d3327fc8633fe51ee8db07d862e16446d456814b4d2e9764cfbd19dee0475113%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true