Cover Feature: Competing Roles of Two Kinds of Ligand during Nonclassical Crystallization of Pillared‐Layer Metal‐Organic Frameworks Elucidated Using Microfluidic Systems (Chem. Eur. J. 41/2020)

Microfluidic systems are efficient tools for elucidating the non‐equilibrium state on the crystallization of multi‐component metal–organic frameworks (MOFs). The understanding of the crystallization mechanism makes it possible to predict the synthesis conditions. Based on the experimental analysis u...

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Bibliographic Details
Published in:Chemistry : a European journal 2020-07, Vol.26 (41), p.8830-8830
Main Authors: Tanaka, Yoko, Kitamura, Yu, Kawano, Ryuji, Shoji, Kan, Hiratani, Moe, Honma, Tetsuo, Takaya, Hikaru, Yoshikawa, Hirofumi, Tsuruoka, Takaaki, Tanaka, Daisuke
Format: Article
Language:English
Subjects:
metal-organic frameworks
microflow reactor
nonclassical crystallization mechanism
pillared-layer structure
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Summary:Microfluidic systems are efficient tools for elucidating the non‐equilibrium state on the crystallization of multi‐component metal–organic frameworks (MOFs). The understanding of the crystallization mechanism makes it possible to predict the synthesis conditions. Based on the experimental analysis using microflow reactors, nonclassical crystallization processes are proposed, involving two kinds of intermediate states and the competing roles of two kinds of ligand which promote or suppress nucleation. More information can be found in the Full Paper by R. Kawano, D. Tanaka, et al. on page 8889.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.202002105