Cover Feature: The Influence of Secondary Interactions on the [N−I−N]+ Halogen Bond (Chem. Eur. J. 55/2021)

A three‐center halogen bond modulates the reactivity of a halonium ion and is thereby applicable for controlling the halogenation of alkenes. Chelation, strain, steric hindrance, and electrostatic interactions influence the halonium release rate. Combined experimental and theoretical analysis of the...

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Published in:Chemistry : a European journal 2021-10, Vol.27 (55), p.13661-13661
Main Authors: Lindblad, Sofia, Boróka Németh, Flóra, Földes, Tamás, Heiden, Daniel, Vang, Herh G., Driscoll, Zakarias L., Gonnering, Emily R., Pápai, Imre, Bowling, Nathan, Erdelyi, Mate
Format: Article
Language:English
Subjects:
density functional calculations
halogen bond
iodonium ion
NMR spectroscopy
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container_end_page 13661
container_issue 55
container_start_page 13661
container_title Chemistry : a European journal
container_volume 27
creator Lindblad, Sofia
Boróka Németh, Flóra
Földes, Tamás
Heiden, Daniel
Vang, Herh G.
Driscoll, Zakarias L.
Gonnering, Emily R.
Pápai, Imre
Bowling, Nathan
Erdelyi, Mate
description A three‐center halogen bond modulates the reactivity of a halonium ion and is thereby applicable for controlling the halogenation of alkenes. Chelation, strain, steric hindrance, and electrostatic interactions influence the halonium release rate. Combined experimental and theoretical analysis of the reaction mechanism highlights the impact of secondary interactions, and is expected to provide a handle on the induction of stereoselectivity in electrophilic halogenation. More information can be found in the Full Paper by I. Pápai, N. Bowling, M. Erdelyi et al. (DOI: 10.1002/chem.202102575).
doi_str_mv 10.1002/chem.202103250
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subjects density functional calculations
halogen bond
iodonium ion
NMR spectroscopy
title Cover Feature: The Influence of Secondary Interactions on the [N−I−N]+ Halogen Bond (Chem. Eur. J. 55/2021)
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