Cover Feature: Surface Studies on the Energy Release of the MOST System 2‐Carbethoxy‐3‐Phenyl‐Norbornadiene/Quadricyclane (PENBD/PEQC) on Pt(111) and Ni(111) (Chem. Eur. J. 25/2023)

The energy storage cycle of the molecular solar thermal (MOST) system has been investigated. In particular, upon irradiation, the energy‐lean 2‐carbethoxy‐3‐phenyl‐norbornadiene is converted into its energy‐rich quadricyclane isomer. The energy‐releasing back reaction can be triggered thermally by m...

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Bibliographic Details
Published in:Chemistry : a European journal 2023-05, Vol.29 (25), p.n/a
Main Authors: Hemauer, Felix, Schwaab, Valentin, Freiberger, Eva Marie, Waleska, Natalie J., Leng, Andreas, Weiß, Cornelius, Steinhauer, Johann, Düll, Fabian, Bachmann, Philipp, Hirsch, Andreas, Steinrück, Hans‐Peter, Papp, Christian
Format: Article
Language:English
Subjects:
catalysis
energy storage
MOST system
photoelectron spectroscopy
surface reactions
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Summary:The energy storage cycle of the molecular solar thermal (MOST) system has been investigated. In particular, upon irradiation, the energy‐lean 2‐carbethoxy‐3‐phenyl‐norbornadiene is converted into its energy‐rich quadricyclane isomer. The energy‐releasing back reaction can be triggered thermally by means of a suitable catalyst surface. The differences in the energy landscapes is visualized by sea level and mountains. More information can be found in the Research Article by C. Papp and co‐workers (DOI: 10.1002/chem.202203759). Cover design by F. Hemauer.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.202300994