Highly Efficient and Thermally Durable Luminescence of 1D Eu 3+ Coordination Polymers with Arsenic Bridging Ligands

In this work, bisarsine oxides were evaluated as novel bridging ligands, aiming to develop practical and efficient luminescent lanthanide coordination polymers. We have synthesized one-dimensional (1D) Eu coordination polymers that incorporate bisarsine oxide bridging ligands and hexafluoroacetylace...

Full description

Saved in:
Bibliographic Details
Published in:Chemistry : a European journal 2024-05, p.e202400615
Main Authors: Shimoji, Haruki, Aoyama, Yuto, Inage, Kota, Nakamura, Masashi, Yanagihara, Takumi, Yuhara, Kazuhiro, Kitagawa, Yuichi, Hasegawa, Yasuchika, Ito, Shunichiro, Tanaka, Kazuo, Imoto, Hiroaki, Naka, Kensuke
Format: Article
Language:English
Citations: Items that this one cites
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites cdi_FETCH-LOGICAL-c627-a236516dc4e67d624bd78820a7eb1fe83b2a7e0c8bd2b8d97e40125768152c663
container_end_page
container_issue
container_start_page e202400615
container_title Chemistry : a European journal
container_volume
creator Shimoji, Haruki
Aoyama, Yuto
Inage, Kota
Nakamura, Masashi
Yanagihara, Takumi
Yuhara, Kazuhiro
Kitagawa, Yuichi
Hasegawa, Yasuchika
Ito, Shunichiro
Tanaka, Kazuo
Imoto, Hiroaki
Naka, Kensuke
description In this work, bisarsine oxides were evaluated as novel bridging ligands, aiming to develop practical and efficient luminescent lanthanide coordination polymers. We have synthesized one-dimensional (1D) Eu coordination polymers that incorporate bisarsine oxide bridging ligands and hexafluoroacetylacetonate anions. These polymers exhibited a denser packing of chains compared to analogous polymers bridged with bisphosphine oxides. The coordination polymers demonstrated exceptional thermal stability and substantial emission quantum yields. Additionally, the bisarsine oxides induced a pronounced polarization effect, facilitating a sensitive electric dipole transition that yields considerably narrow band red emission. Remarkably, the Eu coordination polymers with bisarsine oxides maintained intense emission even at 550 K. A distinctive feature of these polymers is their heating-induced emission enhancement observed when the temperature was increased from 300 K to 400 K.
doi_str_mv 10.1002/chem.202400615
format article
fullrecord <record><control><sourceid>pubmed_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1002_chem_202400615</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>38591237</sourcerecordid><originalsourceid>FETCH-LOGICAL-c627-a236516dc4e67d624bd78820a7eb1fe83b2a7e0c8bd2b8d97e40125768152c663</originalsourceid><addsrcrecordid>eNo90D1PwzAQBmALgWgprIzIO0rxR2InY0kLRYoEQ_fIsS-JUeJUdiPUf0-qQqc7ne59hwehR0qWlBD2olvol4ywmBBBkys0pwmjEZciuUZzksUyEgnPZuguhG9CSCY4v0UzniYZZVzOUdjapu2OeFPXVltwB6ycwbsWfK-66b4evao6wMXYWwdBg9OAhxrTNd6MmD_jfBi8sU4d7ODw19Ade_AB_9hDi1c-gLMav3prGusaXNhmag_36KZWXYCHv7lAu7fNLt9Gxef7R74qIi2YjBTjIqHC6BiENILFlZFpyoiSUNEaUl6xaSU6rQyrUpNJiAlliRTpRKCF4Au0PNdqP4TgoS733vbKH0tKyhNeecIrL3hT4Okc2I9VD-by_q_FfwGnuWrC</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Highly Efficient and Thermally Durable Luminescence of 1D Eu 3+ Coordination Polymers with Arsenic Bridging Ligands</title><source>Wiley-Blackwell Read &amp; Publish Collection</source><creator>Shimoji, Haruki ; Aoyama, Yuto ; Inage, Kota ; Nakamura, Masashi ; Yanagihara, Takumi ; Yuhara, Kazuhiro ; Kitagawa, Yuichi ; Hasegawa, Yasuchika ; Ito, Shunichiro ; Tanaka, Kazuo ; Imoto, Hiroaki ; Naka, Kensuke</creator><creatorcontrib>Shimoji, Haruki ; Aoyama, Yuto ; Inage, Kota ; Nakamura, Masashi ; Yanagihara, Takumi ; Yuhara, Kazuhiro ; Kitagawa, Yuichi ; Hasegawa, Yasuchika ; Ito, Shunichiro ; Tanaka, Kazuo ; Imoto, Hiroaki ; Naka, Kensuke</creatorcontrib><description>In this work, bisarsine oxides were evaluated as novel bridging ligands, aiming to develop practical and efficient luminescent lanthanide coordination polymers. We have synthesized one-dimensional (1D) Eu coordination polymers that incorporate bisarsine oxide bridging ligands and hexafluoroacetylacetonate anions. These polymers exhibited a denser packing of chains compared to analogous polymers bridged with bisphosphine oxides. The coordination polymers demonstrated exceptional thermal stability and substantial emission quantum yields. Additionally, the bisarsine oxides induced a pronounced polarization effect, facilitating a sensitive electric dipole transition that yields considerably narrow band red emission. Remarkably, the Eu coordination polymers with bisarsine oxides maintained intense emission even at 550 K. A distinctive feature of these polymers is their heating-induced emission enhancement observed when the temperature was increased from 300 K to 400 K.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.202400615</identifier><identifier>PMID: 38591237</identifier><language>eng</language><publisher>Germany</publisher><ispartof>Chemistry : a European journal, 2024-05, p.e202400615</ispartof><rights>2024 Wiley-VCH GmbH.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c627-a236516dc4e67d624bd78820a7eb1fe83b2a7e0c8bd2b8d97e40125768152c663</cites><orcidid>0000-0002-4516-6296</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/38591237$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Shimoji, Haruki</creatorcontrib><creatorcontrib>Aoyama, Yuto</creatorcontrib><creatorcontrib>Inage, Kota</creatorcontrib><creatorcontrib>Nakamura, Masashi</creatorcontrib><creatorcontrib>Yanagihara, Takumi</creatorcontrib><creatorcontrib>Yuhara, Kazuhiro</creatorcontrib><creatorcontrib>Kitagawa, Yuichi</creatorcontrib><creatorcontrib>Hasegawa, Yasuchika</creatorcontrib><creatorcontrib>Ito, Shunichiro</creatorcontrib><creatorcontrib>Tanaka, Kazuo</creatorcontrib><creatorcontrib>Imoto, Hiroaki</creatorcontrib><creatorcontrib>Naka, Kensuke</creatorcontrib><title>Highly Efficient and Thermally Durable Luminescence of 1D Eu 3+ Coordination Polymers with Arsenic Bridging Ligands</title><title>Chemistry : a European journal</title><addtitle>Chemistry</addtitle><description>In this work, bisarsine oxides were evaluated as novel bridging ligands, aiming to develop practical and efficient luminescent lanthanide coordination polymers. We have synthesized one-dimensional (1D) Eu coordination polymers that incorporate bisarsine oxide bridging ligands and hexafluoroacetylacetonate anions. These polymers exhibited a denser packing of chains compared to analogous polymers bridged with bisphosphine oxides. The coordination polymers demonstrated exceptional thermal stability and substantial emission quantum yields. Additionally, the bisarsine oxides induced a pronounced polarization effect, facilitating a sensitive electric dipole transition that yields considerably narrow band red emission. Remarkably, the Eu coordination polymers with bisarsine oxides maintained intense emission even at 550 K. A distinctive feature of these polymers is their heating-induced emission enhancement observed when the temperature was increased from 300 K to 400 K.</description><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNo90D1PwzAQBmALgWgprIzIO0rxR2InY0kLRYoEQ_fIsS-JUeJUdiPUf0-qQqc7ne59hwehR0qWlBD2olvol4ywmBBBkys0pwmjEZciuUZzksUyEgnPZuguhG9CSCY4v0UzniYZZVzOUdjapu2OeFPXVltwB6ycwbsWfK-66b4evao6wMXYWwdBg9OAhxrTNd6MmD_jfBi8sU4d7ODw19Ade_AB_9hDi1c-gLMav3prGusaXNhmag_36KZWXYCHv7lAu7fNLt9Gxef7R74qIi2YjBTjIqHC6BiENILFlZFpyoiSUNEaUl6xaSU6rQyrUpNJiAlliRTpRKCF4Au0PNdqP4TgoS733vbKH0tKyhNeecIrL3hT4Okc2I9VD-by_q_FfwGnuWrC</recordid><startdate>20240514</startdate><enddate>20240514</enddate><creator>Shimoji, Haruki</creator><creator>Aoyama, Yuto</creator><creator>Inage, Kota</creator><creator>Nakamura, Masashi</creator><creator>Yanagihara, Takumi</creator><creator>Yuhara, Kazuhiro</creator><creator>Kitagawa, Yuichi</creator><creator>Hasegawa, Yasuchika</creator><creator>Ito, Shunichiro</creator><creator>Tanaka, Kazuo</creator><creator>Imoto, Hiroaki</creator><creator>Naka, Kensuke</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-4516-6296</orcidid></search><sort><creationdate>20240514</creationdate><title>Highly Efficient and Thermally Durable Luminescence of 1D Eu 3+ Coordination Polymers with Arsenic Bridging Ligands</title><author>Shimoji, Haruki ; Aoyama, Yuto ; Inage, Kota ; Nakamura, Masashi ; Yanagihara, Takumi ; Yuhara, Kazuhiro ; Kitagawa, Yuichi ; Hasegawa, Yasuchika ; Ito, Shunichiro ; Tanaka, Kazuo ; Imoto, Hiroaki ; Naka, Kensuke</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c627-a236516dc4e67d624bd78820a7eb1fe83b2a7e0c8bd2b8d97e40125768152c663</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shimoji, Haruki</creatorcontrib><creatorcontrib>Aoyama, Yuto</creatorcontrib><creatorcontrib>Inage, Kota</creatorcontrib><creatorcontrib>Nakamura, Masashi</creatorcontrib><creatorcontrib>Yanagihara, Takumi</creatorcontrib><creatorcontrib>Yuhara, Kazuhiro</creatorcontrib><creatorcontrib>Kitagawa, Yuichi</creatorcontrib><creatorcontrib>Hasegawa, Yasuchika</creatorcontrib><creatorcontrib>Ito, Shunichiro</creatorcontrib><creatorcontrib>Tanaka, Kazuo</creatorcontrib><creatorcontrib>Imoto, Hiroaki</creatorcontrib><creatorcontrib>Naka, Kensuke</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shimoji, Haruki</au><au>Aoyama, Yuto</au><au>Inage, Kota</au><au>Nakamura, Masashi</au><au>Yanagihara, Takumi</au><au>Yuhara, Kazuhiro</au><au>Kitagawa, Yuichi</au><au>Hasegawa, Yasuchika</au><au>Ito, Shunichiro</au><au>Tanaka, Kazuo</au><au>Imoto, Hiroaki</au><au>Naka, Kensuke</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Highly Efficient and Thermally Durable Luminescence of 1D Eu 3+ Coordination Polymers with Arsenic Bridging Ligands</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chemistry</addtitle><date>2024-05-14</date><risdate>2024</risdate><spage>e202400615</spage><pages>e202400615-</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><abstract>In this work, bisarsine oxides were evaluated as novel bridging ligands, aiming to develop practical and efficient luminescent lanthanide coordination polymers. We have synthesized one-dimensional (1D) Eu coordination polymers that incorporate bisarsine oxide bridging ligands and hexafluoroacetylacetonate anions. These polymers exhibited a denser packing of chains compared to analogous polymers bridged with bisphosphine oxides. The coordination polymers demonstrated exceptional thermal stability and substantial emission quantum yields. Additionally, the bisarsine oxides induced a pronounced polarization effect, facilitating a sensitive electric dipole transition that yields considerably narrow band red emission. Remarkably, the Eu coordination polymers with bisarsine oxides maintained intense emission even at 550 K. A distinctive feature of these polymers is their heating-induced emission enhancement observed when the temperature was increased from 300 K to 400 K.</abstract><cop>Germany</cop><pmid>38591237</pmid><doi>10.1002/chem.202400615</doi><orcidid>https://orcid.org/0000-0002-4516-6296</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 0947-6539
ispartof Chemistry : a European journal, 2024-05, p.e202400615
issn 0947-6539
1521-3765
language eng
recordid cdi_crossref_primary_10_1002_chem_202400615
source Wiley-Blackwell Read & Publish Collection
title Highly Efficient and Thermally Durable Luminescence of 1D Eu 3+ Coordination Polymers with Arsenic Bridging Ligands
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-26T05%3A47%3A44IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-pubmed_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Highly%20Efficient%20and%20Thermally%20Durable%20Luminescence%20of%201D%20Eu%203+%20Coordination%20Polymers%20with%20Arsenic%20Bridging%20Ligands&rft.jtitle=Chemistry%20:%20a%20European%20journal&rft.au=Shimoji,%20Haruki&rft.date=2024-05-14&rft.spage=e202400615&rft.pages=e202400615-&rft.issn=0947-6539&rft.eissn=1521-3765&rft_id=info:doi/10.1002/chem.202400615&rft_dat=%3Cpubmed_cross%3E38591237%3C/pubmed_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c627-a236516dc4e67d624bd78820a7eb1fe83b2a7e0c8bd2b8d97e40125768152c663%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/38591237&rfr_iscdi=true