A Facile Approach to Synthesis of the Di-O-methyl Ethers of （-）-Agatharesinol, （-）-Sugiresinol, （＋）-Nyasol and （＋）-Tetrahydronyasol

The facile enantioselective synthesis of the di-O-methyl ethers of （-）-agatharesinol （1b）, （-）-sugiresionl （2b）, （＋）-nyasol （3b） and （＋）-tetrahydronyasol （4） were achieved in high yield. The absolute configuration of （＋）-3a was confirmed via first total synthesis of （＋）-3b and （＋）-4....

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Bibliographic Details
Published in:Chinese journal of chemistry 2007-05, Vol.25 (5), p.688-693
Main Author: 权伟国 俞斌勋 张基勇 梁其任 孙永泉 厍学功 潘鑫复
Format: Article
Language:English
Subjects:
(+)-nyasol
(+)-tetrahydronyasol
(−)-sugiresinol
di-O-methyl ethers of (−)-agatharesinol
synthesis
二-O-甲醚
敏捷合成方法
木脂紊类化合物
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Summary:The facile enantioselective synthesis of the di-O-methyl ethers of （-）-agatharesinol （1b）, （-）-sugiresionl （2b）, （＋）-nyasol （3b） and （＋）-tetrahydronyasol （4） were achieved in high yield. The absolute configuration of （＋）-3a was confirmed via first total synthesis of （＋）-3b and （＋）-4.
ISSN:1001-604X
1614-7065
DOI:10.1002/cjoc.200790129