Studies on the Reactions of Fluoroalkylazides with Electron-deficient Alkenes

The 1,3‐dipolar cycloaddition of fluoroalkylazides with electron deficient olefins was studied. A series of fluoroalkylated triazoline and pyrazolines were synthesized by this method. A ring opening and diazo intermediate mechanism was proposed.

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Bibliographic Details
Published in:Chinese journal of chemistry 2008-10, Vol.26 (10), p.1887-1892
Main Authors: SUN, Qing-Rui, CHEN, Zi-Xian, LI, Shan, WU, Yong-Ming, TIAN, Wei-Sheng
Format: Article
Language:English
Subjects:
1,3‐dipolar cycloaddition
3-dipolar cycloaddition
fluoroalkylated pyrazoline
fluoroalkylated triazoline
fluoroalkylazide
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Description
Summary:The 1,3‐dipolar cycloaddition of fluoroalkylazides with electron deficient olefins was studied. A series of fluoroalkylated triazoline and pyrazolines were synthesized by this method. A ring opening and diazo intermediate mechanism was proposed.
ISSN:1001-604X
1614-7065
DOI:10.1002/cjoc.200890339