Studies on the Reactions of Fluoroalkylazides with Electron-deficient Alkenes
The 1,3‐dipolar cycloaddition of fluoroalkylazides with electron deficient olefins was studied. A series of fluoroalkylated triazoline and pyrazolines were synthesized by this method. A ring opening and diazo intermediate mechanism was proposed.
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Published in: | Chinese journal of chemistry 2008-10, Vol.26 (10), p.1887-1892 |
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cited_by | cdi_FETCH-LOGICAL-c3279-6818a0cb854709697832d33f015ae6186fd2e6458b02e9a42aee66a8bb24c15b3 |
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cites | cdi_FETCH-LOGICAL-c3279-6818a0cb854709697832d33f015ae6186fd2e6458b02e9a42aee66a8bb24c15b3 |
container_end_page | 1892 |
container_issue | 10 |
container_start_page | 1887 |
container_title | Chinese journal of chemistry |
container_volume | 26 |
creator | SUN, Qing-Rui CHEN, Zi-Xian LI, Shan WU, Yong-Ming TIAN, Wei-Sheng |
description | The 1,3‐dipolar cycloaddition of fluoroalkylazides with electron deficient olefins was studied. A series of fluoroalkylated triazoline and pyrazolines were synthesized by this method. A ring opening and diazo intermediate mechanism was proposed. |
doi_str_mv | 10.1002/cjoc.200890339 |
format | article |
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A series of fluoroalkylated triazoline and pyrazolines were synthesized by this method. A ring opening and diazo intermediate mechanism was proposed.</description><identifier>ISSN: 1001-604X</identifier><identifier>EISSN: 1614-7065</identifier><identifier>DOI: 10.1002/cjoc.200890339</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>1,3‐dipolar cycloaddition ; 3-dipolar cycloaddition ; fluoroalkylated pyrazoline ; fluoroalkylated triazoline ; fluoroalkylazide</subject><ispartof>Chinese journal of chemistry, 2008-10, Vol.26 (10), p.1887-1892</ispartof><rights>Copyright © 2008 SIOC, CAS, Shanghai & WILEY‐VCH Verlag GmbH & Co. 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Chem</addtitle><description>The 1,3‐dipolar cycloaddition of fluoroalkylazides with electron deficient olefins was studied. A series of fluoroalkylated triazoline and pyrazolines were synthesized by this method. A ring opening and diazo intermediate mechanism was proposed.</description><subject>1,3‐dipolar cycloaddition</subject><subject>3-dipolar cycloaddition</subject><subject>fluoroalkylated pyrazoline</subject><subject>fluoroalkylated triazoline</subject><subject>fluoroalkylazide</subject><issn>1001-604X</issn><issn>1614-7065</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNqFkE1Lw0AQQBdRsFavnvMHUmd3k_04ltLWj2rBKoqXZbOZ0G1jItmUWn-9KRXx5mmG4b05PEIuKQwoALtyq9oNGIDSwLk-Ij0qaBJLEOlxtwPQWEDyekrOQlh1vJRM9Mj9ot3kHkNUV1G7xOgRrWt9XXWHIpqUm7qpbbnelfbL5x219e0yGpfo2qau4hwL7zxWbTQs11hhOCcnhS0DXvzMPnmejJ9G1_FsPr0ZDWex40zqWCiqLLhMpYkELbRUnOWcF0BTi4IqUeQMRZKqDBhqmzCLKIRVWcYSR9OM98ng8Nc1dQgNFuaj8e-22RkKZh_D7GOY3xidoA_C1pe4-4c2o9v56K8bH1wfWvz8dW2zNkJymZqXh6mBOy0XiXozlH8DD_xy2A</recordid><startdate>200810</startdate><enddate>200810</enddate><creator>SUN, Qing-Rui</creator><creator>CHEN, Zi-Xian</creator><creator>LI, Shan</creator><creator>WU, Yong-Ming</creator><creator>TIAN, Wei-Sheng</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>200810</creationdate><title>Studies on the Reactions of Fluoroalkylazides with Electron-deficient Alkenes</title><author>SUN, Qing-Rui ; CHEN, Zi-Xian ; LI, Shan ; WU, Yong-Ming ; TIAN, Wei-Sheng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3279-6818a0cb854709697832d33f015ae6186fd2e6458b02e9a42aee66a8bb24c15b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>1,3‐dipolar cycloaddition</topic><topic>3-dipolar cycloaddition</topic><topic>fluoroalkylated pyrazoline</topic><topic>fluoroalkylated triazoline</topic><topic>fluoroalkylazide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>SUN, Qing-Rui</creatorcontrib><creatorcontrib>CHEN, Zi-Xian</creatorcontrib><creatorcontrib>LI, Shan</creatorcontrib><creatorcontrib>WU, Yong-Ming</creatorcontrib><creatorcontrib>TIAN, Wei-Sheng</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>Chinese journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>SUN, Qing-Rui</au><au>CHEN, Zi-Xian</au><au>LI, Shan</au><au>WU, Yong-Ming</au><au>TIAN, Wei-Sheng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Studies on the Reactions of Fluoroalkylazides with Electron-deficient Alkenes</atitle><jtitle>Chinese journal of chemistry</jtitle><addtitle>Chin. J. Chem</addtitle><date>2008-10</date><risdate>2008</risdate><volume>26</volume><issue>10</issue><spage>1887</spage><epage>1892</epage><pages>1887-1892</pages><issn>1001-604X</issn><eissn>1614-7065</eissn><abstract>The 1,3‐dipolar cycloaddition of fluoroalkylazides with electron deficient olefins was studied. A series of fluoroalkylated triazoline and pyrazolines were synthesized by this method. A ring opening and diazo intermediate mechanism was proposed.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/cjoc.200890339</doi><tpages>6</tpages></addata></record> |
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language | eng |
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source | Wiley-Blackwell Read & Publish Collection |
subjects | 1,3‐dipolar cycloaddition 3-dipolar cycloaddition fluoroalkylated pyrazoline fluoroalkylated triazoline fluoroalkylazide |
title | Studies on the Reactions of Fluoroalkylazides with Electron-deficient Alkenes |
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