Studies on the Reactions of Fluoroalkylazides with Electron-deficient Alkenes

The 1,3‐dipolar cycloaddition of fluoroalkylazides with electron deficient olefins was studied. A series of fluoroalkylated triazoline and pyrazolines were synthesized by this method. A ring opening and diazo intermediate mechanism was proposed.

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Published in:Chinese journal of chemistry 2008-10, Vol.26 (10), p.1887-1892
Main Authors: SUN, Qing-Rui, CHEN, Zi-Xian, LI, Shan, WU, Yong-Ming, TIAN, Wei-Sheng
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Language:English
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cited_by cdi_FETCH-LOGICAL-c3279-6818a0cb854709697832d33f015ae6186fd2e6458b02e9a42aee66a8bb24c15b3
cites cdi_FETCH-LOGICAL-c3279-6818a0cb854709697832d33f015ae6186fd2e6458b02e9a42aee66a8bb24c15b3
container_end_page 1892
container_issue 10
container_start_page 1887
container_title Chinese journal of chemistry
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creator SUN, Qing-Rui
CHEN, Zi-Xian
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WU, Yong-Ming
TIAN, Wei-Sheng
description The 1,3‐dipolar cycloaddition of fluoroalkylazides with electron deficient olefins was studied. A series of fluoroalkylated triazoline and pyrazolines were synthesized by this method. A ring opening and diazo intermediate mechanism was proposed.
doi_str_mv 10.1002/cjoc.200890339
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source Wiley-Blackwell Read & Publish Collection
subjects 1,3‐dipolar cycloaddition
3-dipolar cycloaddition
fluoroalkylated pyrazoline
fluoroalkylated triazoline
fluoroalkylazide
title Studies on the Reactions of Fluoroalkylazides with Electron-deficient Alkenes
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